CAREY: ORGANIC CHEMISTRY
10th Edition
ISBN: 9781260364002
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Question
Chapter 21, Problem 57P
Interpretation Introduction
Interpretation:
The reasonable mechanism for each of the given reactions is to be stated.
Concept introduction:
The replacement or substitution of one
In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.
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Please help me with # 4 and 5. Thanks in advance!
A small artisanal cheesemaker is testing the acidity of their milk
before it coagulates. During fermentation, bacteria produce lactic
acid (K₁ = 1.4 x 104), a weak acid that helps to curdle the milk and
develop flavor. The cheesemaker has measured that the developing
mixture contains lactic acid at an initial concentration of 0.025 M.
Your task is to calculate the pH of this mixture and determine whether
it meets the required acidity for proper cheese development. To
achieve the best flavor, texture and reduce/control microbial growth,
the pH range needs to be between pH 4.6 and 5.0.
Assumptions:
Lactic acid is a monoprotic acid
H
H
:0:0:
H-C-C
H
:0:
O-H
Figure 1: Lewis Structure for Lactic Acid
For simplicity, you can use the generic formula HA to represent the acid
You can assume lactic acid dissociation is in water as milk is mostly water.
Temperature is 25°C
1. Write the K, expression for the dissociation of lactic acid in the space provided. Do not forget to
include state symbols.…
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product
structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s).
Be sure to account for all bond-breaking and bond-making steps.
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:0
H.
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:0:
:6:
S:
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Select to Edit Arrows
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Select to Edit Arrows
H
:0:
H
:CI:
Rotation
Select to Edit Arrows
H.
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:0:
:0:
:0:
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Chapter 21 Solutions
CAREY: ORGANIC CHEMISTRY
Ch. 21.1 - Prob. 1PCh. 21.1 - Prob. 2PCh. 21.1 - Prob. 3PCh. 21.1 - Prob. 4PCh. 21.1 - Prob. 5PCh. 21.2 - Prob. 6PCh. 21.2 - Prob. 7PCh. 21.2 - Prob. 8PCh. 21.3 - Prob. 9PCh. 21.3 - Prob. 10P
Ch. 21.3 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - Problem 21.15 Write the structure of the Dieckmann...Ch. 21.5 - Prob. 16PCh. 21.5 - Prob. 17PCh. 21.6 - Prob. 18PCh. 21.6 - Prob. 19PCh. 21.6 - Prob. 20PCh. 21.6 - Prob. 21PCh. 21.6 - Prob. 22PCh. 21.7 - Prob. 23PCh. 21.8 - Problem 21.24 Mesityl oxide is an industrial...Ch. 21.8 - Prob. 25PCh. 21.8 - Prob. 26PCh. 21.8 - Prob. 27PCh. 21.8 - Prob. 28PCh. 21 - Prob. 29PCh. 21 - Terreic acid, a naturally occurring antibiotic...Ch. 21 - Prob. 31PCh. 21 - Prob. 32PCh. 21 - Prob. 33PCh. 21 - Prob. 34PCh. 21 - Give the structure of the expected organic product...Ch. 21 - Prob. 36PCh. 21 - Prob. 37PCh. 21 - Prob. 38PCh. 21 - Prob. 39PCh. 21 - Give the structure of the principal organic...Ch. 21 - Prob. 41PCh. 21 - Prob. 42PCh. 21 - Prob. 43PCh. 21 - Prob. 44PCh. 21 - Prob. 45PCh. 21 - Prob. 46PCh. 21 - Prob. 47PCh. 21 - The use of epoxides as alkylating agents for...Ch. 21 - Prob. 49PCh. 21 - Show how you could prepare each of the following...Ch. 21 - Prob. 51PCh. 21 - Prob. 52PCh. 21 - Prob. 53PCh. 21 - Prob. 54PCh. 21 - The - methylene ketone sarkomycin has an...Ch. 21 - - Lactone can be prepared in good yield from...Ch. 21 - Prob. 57PCh. 21 - Prob. 58DSPCh. 21 - The Enolate Chemistry of Dianionss The synthetic...Ch. 21 - Prob. 60DSPCh. 21 - Prob. 61DSPCh. 21 - Prob. 62DSPCh. 21 - Prob. 63DSP
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