The correct naming of the given compounds is to be stated. Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds. Carbonyl group is present in both aldehydes and ketones . Aldehydes are named by using the suffix “ − al ” and ketones are named by using the suffix “ − one ”. To determine: The name of the following given compound.

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Answer 1

Question

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Google

Print Last Name, First Name Initial Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 4th total • 6H total 래 • 4H total 21 total ZH 2H Statistical H < 3° C-H weakest - product abstraction here bund leads to thermo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Product 6 Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl Waterfox

Answer 2

Question

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 6

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 7

Chapter 21, Problem 55E

(a)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 8

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 9

(b)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 10

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 11

(c)

Interpretation Introduction

Interpretation: The correct naming of the given compounds is to be stated.

Concept introduction: The IUPAC nomenclature of organic compound is used for naming organic compounds.

Carbonyl group is present in both aldehydes and ketones. Aldehydes are named by using the suffix “ −al ” and ketones are named by using the suffix “ −one ”.

To determine: The name of the following given compound.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The IUPAC nomenclature of organic compound is used for naming organic compounds. Carbonyl group is present in aldehydes and ketones.

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Chapter 21 Solutions