The formulas of the given complex compounds are to be stated. Concept introduction: Rules followed in the naming of coordination compound: Greek prefix is used to express the number of ligands. Roman numeral is used to denote the oxidation state of metal ion. In case of more than one type of ligand present in a compound, they are named alphabetically. The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals. If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt. To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Question

How could you distinguish between each pair of compounds below using IR? For each pair citeone bond and it’s frequency that you could use to distinguish between them. Please provide thorough analysis to apply into further problems.

Answer 1

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 2

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 3

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 4

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 5

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 6

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Answer 7

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Answer 8

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

Answer 9

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

Answer 10

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

Answer 11

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

Answer 12

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 13

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 14

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Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

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Chapter 21 Solutions