Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 21, Problem 23E
Interpretation Introduction
Interpretation: The electron configuration of each element
Concept introduction: Valence electrons are filled in four principal orbitals according to the energy levels. The four orbitals are
The metals from group
The distribution of electrons among different orbitals is given by electron configuration.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Write electron configurations for the following ions.
a. Ni2+
b. Cd2+
c. Zr3+ and Zr4+
d. Os2+ and Os3+
Which of the following system has maximum
number of unpaired electrons?
O A. d*(Octahedral,Low spin)
B. d° (tetrahedral)
C. d (Octahedral, low spin)
O D. d° (Octahedral)
Why do ligands cause the d orbitals of a transition metal ion to cease being degenerate?
A. New molecular orbitals are formed via atomic orbital overlapt
B. There is repulsion between the ligands and the d orbitals.
C. They destabilize the ion nucleus
D. Donation of electrons to the metal ion results in redox chemistry
Chapter 21 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Prob. 5RQCh. 21 - Prob. 6RQCh. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - What is the maximum number of unpaired d electrons...Ch. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21QCh. 21 - Prob. 22QCh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Consider aqueous solutions of the following...Ch. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 72ECh. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 77AECh. 21 - Prob. 78AECh. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 83AECh. 21 - Prob. 84AECh. 21 - Prob. 85AECh. 21 - Prob. 86AECh. 21 - Carbon monoxide is toxic because it binds more...Ch. 21 - Prob. 88AECh. 21 - Prob. 89CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 91CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 93CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 97CPCh. 21 - Prob. 98CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 100CPCh. 21 - Prob. 101CPCh. 21 - Prob. 102CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - Ethylenediaminetetraacetate (EDTA4 ) is used as a...Ch. 21 - Prob. 105CPCh. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The standard reduction potential for the reaction [Co( H 2 O)6]3+(aq)+e[CO( H 2 O)6]2+(aq) is about 1.8 V. The reduction potential for the reaction [Co( NH 3 )6]3+(aq)+e[Co( NH 3 )6]2+(aq) is +0.1 V. Calculate the cell potentials to show whether the complex ions,. [Co( H 2 O)6]2+ and or [Co( NH 3 )6]2+, can be oxidized to the corresponding Cobalt (III) complex by oxygen.arrow_forwardWrite an abbreviated orbital diagram and determine the number of unpaired electrons in each species in Question 31.arrow_forwardGive the oxidation state of the metal, number of d electrons, and the number of unpaired electrons predicted for [CO(NH3)6]Cl3.arrow_forward
- Chelating ligands often form more stable complex ions than the corresponding monodentate ligands with the same donor atoms. For example, Ni2+(aq)+6NH3(aq)Ni(NH3)62+(aq)K=3.2108Ni2+(aq)+3en(aq)Ni(en)32+(aq)K=1.61018Ni2+(aq)+penten(aq)Ni(penten)2+(aq)K=2.01019 where en is ethylenediamine and penten is This increased stability is called the chelate effect. Based on bond energies, would you expect the enthalpy changes for the above reactions to be very different? What is the order (from least favorable to most favorable) of the entropy changes for the above reactions? How do the values of the formation constants correlate with S? How can this be used to explain the chelate effect?arrow_forwardWhich first-row transition metal(s) has the following highest possible oxidation state?a. +3 b. +7 c. +4arrow_forwardOn adding sodium hydroxide solution to aluminum salt solution is formed .. a. A gelatinous white ppt. dissolves in an excess of ammonium hydroxide b. White color c. Yellow ppt. which dissolves in dil. acids d. A gelatinous white ppt. which dissolves in an excess of sodium hydroxidearrow_forward
- The element which has the electronic configuration [Kr), 55, 4d is IS a. Paramagnetic in its atomic state b. Paramagnetic at oxidation state +2 c. Diamagnetic at its atomic state d. Diamagnetic colored substancearrow_forwardThe spectrochemical series:a. lists metals ions in order of their oxidation state.b. lists metals ions in order by their color.c. lists ligands in order of their tendency to split d orbitals.d. is used to determine the oxidation state of a central metal atom.e. is used to calculate the crystal field splitting energy of complex ions. deltaS will be positive for the reaction a. 2H2 (g) + O2 (g) → 2H2O (g)b. 2NO2 (g) → N2O4 (g)c. NaF2 (aq) → Na+(aq) + 2F¯(aq)d. 2Hg (l) + O2 (g) → 2HgO (s)e. CO2 (g) → CO2 (s)arrow_forwardWhich of the following is not a factor when predicting Ao? a. Oxidation state of the metal b. Spectrochemical series c. Whether the metal is from n = 3, 4, or 5 d. The geometry of the complex e. The charge on the ligandarrow_forward
- Consider the following complex ions: Cr,0,, MnO, Clo,, and Bro. Determine which statement is false. The oxidation number of chlorine in CIo, is +5. a. b. Oxygen has an oxidation number of-2 in all of the compounds. c. The oxidation number of bromine in Bro is +1. d. The oxidation number of oxygen in each complex ion is -2.arrow_forwardIn the structures below, M represents the central metal atom and the colored spheres represent the bonded groups (ligands). Different ligands are labeled with different letter designations. Classify each pair of ions by the type of isomer they represent or as identical ions. a. Coordination isomers b. Geometric isomers c. optical isomers d. identical ionsarrow_forward22. The following ligands that can form complex compounds with class b metals are the most stable complex compounds are…. a. F- B. Cl- C. br- D. I-arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Introduction to Coordination ComplexesWave Function for Hydrogen atom # All Vital Topics # Quantum Mechanics part -21; Author: Priyanka Jain;https://www.youtube.com/watch?v=GKgNV9dmUHo;License: Standard YouTube License, CC-BY
CBSE Class 12 Chemistry || The d & f Block Elements Part 1 || Full Chapter || By Shiksha House; Author: Best for NEET;https://www.youtube.com/watch?v=LzZWHSdYaxw;License: Standard Youtube License