Concept explainers
(a)
Interpretation:
Lewis acid and Lewis base are to be identified in the reaction of oxalate ion
Concept introduction:
The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.
(b)
Interpretation:
The ligands and donor atoms are to be identified.
Concept introduction:
Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.
(c)
Interpretation:
The coordination number and geometry of the metal present in the complex are to be determined.
Concept introduction:
The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.
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CHEMISTRY-TEXT
- Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forward(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.arrow_forwardProvide the name and identify the oxidation state, coordination number, and the molecular geometry of [Fe(H20)6]3+.arrow_forward
- Draw the geometrical structure of both cis- and trans-forms of K[Cr(C2O4)2(H2O)2].arrow_forwardWhat is the theoretical percentage by weight of Cr in K[Cr(C2O4)2(H2O)2]·2H2Oarrow_forwardExplain how the diphosphate ion, [O3P−O−PO3]4−, can function as a water softener that prevents the precipitation of Fe2+ as an insoluble iron salt.arrow_forward
- Predict the products of each of the following reactions and then balance the chemical equations.(a) Fe is heated in an atmosphere of steam.(b) NaOH is added to a solution of Fe(NO3)3.(c) FeSO4 is added to an acidic solution of KMnO4.(d) Fe is added to a dilute solution of H2SO4.(e) A solution of Fe(NO3)2 and HNO3 is allowed to stand in air.(f) FeCO3 is added to a solution of HClO4.(g) Fe is heated in air.arrow_forward(a) Give the chemical name of Ir(CO)CI(PPh 3 ) 2 (either of the two isomers). (b) Sketch all isomers of the octahedral complex Cr(H2O), FBrCl (hint: there are five, and two of the five are enantiomers of each other).arrow_forwardFor each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) carbonate, CO32−, (b) ethane, C2H6.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning