(a) Interpretation: The oxidation state of the metal in complex (NH 4 ) 3 [ RhCl 6 ] needs to be determined. Concept introduction: The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number. In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

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Answer 1

Question

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm

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Answer 2

Question

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

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Answer 3

Question

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

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Answer 4

Question

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

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Answer 5

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 6

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 7

Chapter 21, Problem 21.67SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state of the metal in complex (NH4)3[RhCl6] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The oxidation state of the metal in complex [Cr(NH3)4(SCN)2] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The oxidation state of the metal in complex [Cu(en)2]SO4 needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The oxidation state of the metal in complex Na2[Mn(EDTA)] needs to be determined.

Concept introduction:

The extent of oxidation of the atom in the compound is the oxidation number or oxidation state. It is indicated as a positive or negative number.

In other words, it indicates the loss of electrons of the atom in a chemical compound. This indicates the number of electrons that an atom can gain or lose.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains that the oxidation state of the metal in complex left[Cr(NH_4)/2right] needs to be determined.

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