Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 21, Problem 21.58E
Interpretation Introduction

Interpretation:

The reason as to why the vacuum systems should not have hydrocarbons is to be explained.

Concept introduction:

The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.

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For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table  and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
A molecule shows peaks at 1379, 1327, 1249, 739 cm-1. Draw a diagram of the energy levels for such a molecule. Draw arrows for the possible transitions that could occur for the molecule. In the diagram imagine exciting an electron, what are its various options for getting back to the ground state? What process would promote radiation less decay? What do you expect for the lifetime of an electron in the T1 state? Why is phosphorescence emission weak in most substances? What could you do to a sample to enhance the likelihood that phosphorescence would occur over radiationless decay?
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Chapter 21 Solutions

Physical Chemistry

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