The accomplishment of the given multistep synthesis is to be stated. Concept introduction: Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone . Aldehyde on reaction with silver ion convert into carboxylic acid , however, ketone does not show reaction with silver ion.

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Answer 1

Question

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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A small artisanal cheesemaker is testing the acidity of their milk before it coagulates. During fermentation, bacteria produce lactic acid (K₁ = 1.4 x 104), a weak acid that helps to curdle the milk and develop flavor. The cheesemaker has measured that the developing mixture contains lactic acid at an initial concentration of 0.025 M. Your task is to calculate the pH of this mixture and determine whether it meets the required acidity for proper cheese development. To achieve the best flavor, texture and reduce/control microbial growth, the pH range needs to be between pH 4.6 and 5.0. Assumptions: Lactic acid is a monoprotic acid H H :0:0: H-C-C H :0: O-H Figure 1: Lewis Structure for Lactic Acid For simplicity, you can use the generic formula HA to represent the acid You can assume lactic acid dissociation is in water as milk is mostly water. Temperature is 25°C 1. Write the K, expression for the dissociation of lactic acid in the space provided. Do not forget to include state symbols.…

Answer 2

Question

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Answer 3

Question

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Answer 4

Question

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 6

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

Answer 7

Chapter 21, Problem 21.57SP

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone. Aldehyde on reaction with silver ion convert into carboxylic acid, however, ketone does not show reaction with silver ion.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author explains that the multistep synthesis is to be stated. Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone.

Concept explainers

Videos

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Want to see the full answer?

Chapter 21 Solutions

Solution Summary: The author explains that the multistep synthesis is to be stated. Ozone molecule on reaction with alkene and dimethyl sulphide converts it into aldehyde or ketone.

Concept explainers

Videos

Interpretation: The accomplishment of the given multistep synthesis is to be stated. Concept introduction: Acid chloride on reaction with ammonia gives amide.

Interpretation: The accomplishment of the given multistep synthesis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation: The accomplishment of the given multistep synthesis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

Acid chloride on reaction with ammonia gives amide.

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation:

The accomplishment of the given multistep synthesis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.