Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 21, Problem 21.56QE
Interpretation Introduction
Interpretation:
Age of the artifact has to be calculated.
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The product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1
and 2 below, in any arrangement you like.
1+2
NaBH3CN
H+
N
Click and drag to start drawing a
structure.
5
Assign this HSQC Spectrum ( please editing clearly on the image)
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
Chapter 21 Solutions
Chemistry: Principles and Practice
Ch. 21 - Prob. 21.1QECh. 21 - Prob. 21.2QECh. 21 - Prob. 21.3QECh. 21 - Prob. 21.4QECh. 21 - Prob. 21.5QECh. 21 - Prob. 21.6QECh. 21 - Prob. 21.7QECh. 21 - Prob. 21.8QECh. 21 - Prob. 21.9QECh. 21 - Prob. 21.10QE
Ch. 21 - Prob. 21.11QECh. 21 - Prob. 21.12QECh. 21 - Prob. 21.13QECh. 21 - Prob. 21.14QECh. 21 - Prob. 21.15QECh. 21 - Prob. 21.16QECh. 21 - Prob. 21.17QECh. 21 - Prob. 21.18QECh. 21 - Prob. 21.19QECh. 21 - Prob. 21.20QECh. 21 - Prob. 21.21QECh. 21 - Prob. 21.22QECh. 21 - Prob. 21.23QECh. 21 - Prob. 21.24QECh. 21 - Prob. 21.25QECh. 21 - Prob. 21.26QECh. 21 - Prob. 21.27QECh. 21 - Prob. 21.28QECh. 21 - Prob. 21.29QECh. 21 - Prob. 21.30QECh. 21 - Prob. 21.31QECh. 21 - Prob. 21.32QECh. 21 - Prob. 21.33QECh. 21 - Prob. 21.34QECh. 21 - Prob. 21.35QECh. 21 - Prob. 21.36QECh. 21 - Prob. 21.37QECh. 21 - Prob. 21.38QECh. 21 - Prob. 21.39QECh. 21 - Prob. 21.40QECh. 21 - Prob. 21.41QECh. 21 - Prob. 21.42QECh. 21 - Prob. 21.43QECh. 21 - Prob. 21.44QECh. 21 - Prob. 21.45QECh. 21 - Prob. 21.46QECh. 21 - Prob. 21.47QECh. 21 - Prob. 21.48QECh. 21 - Prob. 21.49QECh. 21 - Prob. 21.50QECh. 21 - Prob. 21.51QECh. 21 - Prob. 21.52QECh. 21 - Prob. 21.53QECh. 21 - Prob. 21.54QECh. 21 - Prob. 21.55QECh. 21 - Prob. 21.56QECh. 21 - Prob. 21.57QECh. 21 - Prob. 21.58QECh. 21 - Prob. 21.59QECh. 21 - Prob. 21.60QECh. 21 - Prob. 21.61QECh. 21 - Prob. 21.62QECh. 21 - Prob. 21.63QECh. 21 - Prob. 21.64QECh. 21 - Prob. 21.65QE
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- Predict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forward
- The product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forwardExplain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forward
- Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forwardExplanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forward
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