ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 21, Problem 21.36AP
Interpretation Introduction

Interpretation:

The structure, name, and absolute configuration of the end levorotatory product of the given reaction are to be predicted.

Concept introduction:

Esters are formed by the reaction of an acid with an alcohol. The process of formation of esters is known as esterification.

The metal hydride reagents are good reducing agents such as LiAlH4. Lithium aluminum hydride is used in many organic syntheses as a reducing agent.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other.

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI OH woཡི།༠w Br H مه D CI ပ။ Br H, Br Br H₂N OMe R IN Ill N S H CI Br CI CI D OH H 1/111
Draw the two products of the reaction. H₂C. CH₂ H :0: CH3 CH₂ +1
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