Chemistry, Loose-leaf Edition (8th Edition)
8th Edition
ISBN: 9780135210123
Author: Jill Kirsten Robinson, John E. McMurry, Robert C. Fay
Publisher: PEARSON
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Question
Chapter 21, Problem 21.21P
Interpretation Introduction
Interpretation:
The ligand donor atom needs to be determined. The reason for it to act as a ligand donor atom needs to be explained.
Concept introduction:
In any complex, the ligand is an atom or group of atoms which donate electron/s to the central metal atom or ion.
To act as a ligand, the atom must have excess of electron/s and the central metal should have deficiency of electrons.
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Students have asked these similar questions
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 21 Solutions
Chemistry, Loose-leaf Edition (8th Edition)
Ch. 21 - Prob. 21.1PCh. 21 - Prob. 21.2ACh. 21 - Prob. 21.3PCh. 21 - Prob. 21.4ACh. 21 - Prob. 21.5PCh. 21 - Prob. 21.6ACh. 21 - Prob. 21.7PCh. 21 - Prob. 21.8ACh. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A
Ch. 21 - Prob. 21.11PCh. 21 - How many diastereoisomer are possible for the...Ch. 21 - Prob. 21.13PCh. 21 - Consider the following ethylenediamine complexes...Ch. 21 - Prob. 21.15PCh. 21 - Prob. 21.16ACh. 21 - Draw a crystal field energy-level diagram and...Ch. 21 - Prob. 21.18ACh. 21 - Prob. 21.19PCh. 21 - Prob. 21.20ACh. 21 - Prob. 21.21PCh. 21 - Prob. 21.22PCh. 21 - Prob. 21.23PCh. 21 - Prob. 21.24PCh. 21 - Prob. 21.25PCh. 21 - Prob. 21.26CPCh. 21 - Prob. 21.27CPCh. 21 - Prob. 21.28CPCh. 21 - Prob. 21.29CPCh. 21 - CH2 Classify the following ligands as monodentate,...Ch. 21 - Prob. 21.31CPCh. 21 - Prob. 21.32CPCh. 21 - Prob. 21.33CPCh. 21 - Consider the following ethylenediamine complexes....Ch. 21 - Prob. 21.35CPCh. 21 - Prob. 21.36SPCh. 21 - Prob. 21.37SPCh. 21 - Prob. 21.38SPCh. 21 - Prob. 21.39SPCh. 21 - Prob. 21.40SPCh. 21 - Prob. 21.41SPCh. 21 - Prob. 21.42SPCh. 21 - Prob. 21.43SPCh. 21 - Prob. 21.44SPCh. 21 - Prob. 21.45SPCh. 21 - Prob. 21.46SPCh. 21 - Prob. 21.47SPCh. 21 - Prob. 21.48SPCh. 21 - Prob. 21.49SPCh. 21 - Prob. 21.50SPCh. 21 - Prob. 21.51SPCh. 21 - Prob. 21.52SPCh. 21 - Prob. 21.53SPCh. 21 - Prob. 21.54SPCh. 21 - Prob. 21.55SPCh. 21 - Prob. 21.56SPCh. 21 - Prob. 21.57SPCh. 21 - Prob. 21.58SPCh. 21 - Prob. 21.59SPCh. 21 - Prob. 21.60SPCh. 21 - Prob. 21.61SPCh. 21 - What is the coordination number of the metal in...Ch. 21 - Prob. 21.63SPCh. 21 - Prob. 21.64SPCh. 21 - Prob. 21.65SPCh. 21 - Prob. 21.66SPCh. 21 - Prob. 21.67SPCh. 21 - Prob. 21.68SPCh. 21 - Prob. 21.69SPCh. 21 - Draw the structure of the iron oxalate complex...Ch. 21 - Prob. 21.71SPCh. 21 - Prob. 21.72SPCh. 21 - Prob. 21.73SPCh. 21 - Prob. 21.74SPCh. 21 - Prob. 21.75SPCh. 21 - Prob. 21.76SPCh. 21 - Prob. 21.77SPCh. 21 - What is the systematic name for each of the...Ch. 21 - Prob. 21.79SPCh. 21 - Prob. 21.80SPCh. 21 - Prob. 21.81SPCh. 21 - Prob. 21.82SPCh. 21 - Prob. 21.83SPCh. 21 - Prob. 21.84SPCh. 21 - Prob. 21.85SPCh. 21 - Prob. 21.86SPCh. 21 - Prob. 21.87SPCh. 21 - Prob. 21.88SPCh. 21 - Prob. 21.89SPCh. 21 - Prob. 21.90SPCh. 21 - Prob. 21.91SPCh. 21 - Prob. 21.92SPCh. 21 - Prob. 21.93SPCh. 21 - Prob. 21.94SPCh. 21 - Prob. 21.95SPCh. 21 - Prob. 21.96SPCh. 21 - Prob. 21.97SPCh. 21 - Prob. 21.98SPCh. 21 - Prob. 21.99SPCh. 21 - Prob. 21.100SPCh. 21 - Prob. 21.101SPCh. 21 - Prob. 21.102SPCh. 21 - Prob. 21.103SPCh. 21 - Prob. 21.104SPCh. 21 - Prob. 21.105SPCh. 21 - Prob. 21.106SPCh. 21 - Prob. 21.107SPCh. 21 - Prob. 21.108SPCh. 21 - Prob. 21.109SPCh. 21 - Prob. 21.110SPCh. 21 - Prob. 21.111SPCh. 21 - Prob. 21.112SPCh. 21 - Prob. 21.113SPCh. 21 - Prob. 21.114SPCh. 21 - Prob. 21.115SPCh. 21 - Prob. 21.116SPCh. 21 - Prob. 21.117SPCh. 21 - Prob. 21.118SPCh. 21 - Prob. 21.119SPCh. 21 - Prob. 21.120SPCh. 21 - Prob. 21.121SPCh. 21 - Prob. 21.122SPCh. 21 - Prob. 21.123SPCh. 21 - Prob. 21.124SPCh. 21 - Prob. 21.125SPCh. 21 - Prob. 21.126SPCh. 21 - Prob. 21.127SPCh. 21 - Prob. 21.128SPCh. 21 - Prob. 21.129SPCh. 21 - Prob. 21.130MPCh. 21 - Nickel(II) complexes with the formula NiX2L2 ,...Ch. 21 - Prob. 21.132MPCh. 21 - The amount of paramagnetism for a first-series...Ch. 21 - Prob. 21.134MPCh. 21 - Prob. 21.135MPCh. 21 - Prob. 21.136MPCh. 21 - Prob. 21.137MPCh. 21 - Prob. 21.138MPCh. 21 - Chromium forms three isomeric compounds A, B, and...Ch. 21 - Prob. 21.140MPCh. 21 - Prob. 21.141MPCh. 21 - Prob. 21.142MP
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