(a) Interpretation: The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined. Concept introduction: The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory . The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding. The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex. The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

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Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

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Answer 5

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 6

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 7

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains the orbital diagram of the free metal ion and its identity. The number of unpaired electrons in the complex is determined by the valence bond theory.

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Chapter 21 Solutions