Chapter 21, Problem 21.123SP

Interpretation Introduction

(a)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex $\left({\text{NH}}_{\text{4}}\right)\text{[Cr}{\left({\text{H}}_{\text{2}}\text{O}\right)}_{\text{6}}\text{]}{\left({\text{SO}}_{\text{4}}\right)}_{\text{2}}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known to be a part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.

Interpretation Introduction

(b)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex $\text{Mo}{\left(\text{CO}\right)}_{\text{6}}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin.

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known as the part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.

Interpretation Introduction

(c)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex $\left[\text{Ni}{\left({\text{NH}}_{\text{3}}\right)}_{\text{4}}{\left({\text{H}}_{\text{2}}\text{O}\right)}_{\text{2}}\right]{\left({\text{NO}}_{\text{3}}\right)}_{\text{2}}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known as the part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.

Interpretation Introduction

(d)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex ${\text{K}}_{\text{4}}\text{[Os}{\left(\text{CN}\right)}_{\text{6}}\text{]}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known as the part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.

Interpretation Introduction

(e)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex ${\text{[Pt(NH}}_{\text{3}}{\text{)}}_{\text{4}}{\text{](CIO}}_{\text{4}}{\text{)}}_{\text{2}}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known as the part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.

Interpretation Introduction

(f)

Interpretation:

The systematic name, crystal filed energy diagram and the number of unpaired electrons of the complex ${\text{Na}}_{\text{2}}{\text{[Fe(CO)}}_{\text{4}}\text{]}$ along with the oxidation state of the transition metal are to be determined. It is also to be determined that this complex is low spin or high spin

Concept introduction:

The systematic name is defined as the name that is given in a systematic way to a unique group, object or chemical substance. The systematic name is known as the part of the nomenclature.

The crystal field theory is used to describe the degeneracy of electron orbital states.

The oxidation state of an element is defined as the number assigned to the element that represents the number of elements lost or gained by the atom in the given compound.