Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 21, Problem 102RQ
Interpretation Introduction
Interpretation: The experiment that can be performed to test whether the given mechanism is really responsible for the racemization of the given compound is to be determined.
Concept Introduction:
The mechanism of a racemization reaction can be confirmed by detecting the presence of the intermediate in the reaction mixture.
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[Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O
3. Does the value of the equilibrium constant (K) for this reaction increase, decrease, or
remain the same as the concentration of chloride increases? Explain your answer
incorporating the definition of an equilibrium constant.
Part B: True /False
) trans-[Co(en)2Cl2]Cl is a chiral compound
give an example of linkage isomerism.
Chapter 21 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 21 - Prob. 1PECh. 21 - Aluminum chloride crystallizes from aqueous...Ch. 21 - What is the formula of the complex ion that is...Ch. 21 - Prob. 4PECh. 21 - Prob. 5PECh. 21 - Prob. 6PECh. 21 - What is the coordination number of the metal ion...Ch. 21 - What is the coordination number of the metal ion...Ch. 21 - Prob. 9PECh. 21 - Prob. 10PE
Ch. 21 - Prob. 11PECh. 21 - Prob. 12PECh. 21 - The iron metal center in hemoglobin sits in an...Ch. 21 - Prob. 1RQCh. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Complex Ions Use Lewis structures to diagram the...Ch. 21 - Complex Ions
21.6 What must be true about the...Ch. 21 - Prob. 7RQCh. 21 - Complex Ions What is a chelate? Use Lewis...Ch. 21 - Prob. 9RQCh. 21 - Complex Ions Explain how a sale of EDTA4- can...Ch. 21 - Prob. 11RQCh. 21 - Complex Ions
21.12 The cobalt(III) ion, , forms a...Ch. 21 - Prob. 13RQCh. 21 - Complex Ions What is the chelate effect? How does...Ch. 21 - Prob. 15RQCh. 21 - Prob. 16RQCh. 21 - Prob. 17RQCh. 21 - Prob. 18RQCh. 21 - Prob. 19RQCh. 21 - Prob. 20RQCh. 21 - Prob. 21RQCh. 21 - Prob. 22RQCh. 21 - Prob. 23RQCh. 21 - Prob. 24RQCh. 21 - Coordination Number and Structure Draw (a) a...Ch. 21 - Prob. 26RQCh. 21 - Prob. 27RQCh. 21 - Prob. 28RQCh. 21 - Prob. 29RQCh. 21 - Prob. 30RQCh. 21 - Prob. 31RQCh. 21 - Bonding in Metal Complexes
21.32 On appropriate...Ch. 21 - Prob. 33RQCh. 21 - Prob. 34RQCh. 21 - Prob. 35RQCh. 21 - Prob. 36RQCh. 21 - Prob. 37RQCh. 21 - Prob. 38RQCh. 21 - Prob. 39RQCh. 21 - Prob. 40RQCh. 21 - Prob. 41RQCh. 21 - Prob. 42RQCh. 21 - Bonding in Metal Complexes What factors about the...Ch. 21 - Prob. 44RQCh. 21 - Bonding in Metal Complexes The complex [...Ch. 21 - Bonding in Metal Complexes
21.46 Consider the...Ch. 21 - Prob. 47RQCh. 21 - Prob. 48RQCh. 21 - Prob. 49RQCh. 21 - Prob. 50RQCh. 21 - Prob. 51RQCh. 21 - Biological Functions of Metals Ions
21.52 List...Ch. 21 - Prob. 53RQCh. 21 - Prob. 54RQCh. 21 - Prob. 55RQCh. 21 - Write the formula, including its correct charge,...Ch. 21 - Metal Complex Nomenclature How would the following...Ch. 21 - Metal Complex Nomenclature
21.58 How would the...Ch. 21 - Give IUPAC names for each of the following:...Ch. 21 - Prob. 60RQCh. 21 - Prob. 61RQCh. 21 - Prob. 62RQCh. 21 - Coordination Number and Structure
21.63 What is...Ch. 21 - Prob. 64RQCh. 21 - Draw a reasonable structure for (a) [ Zn(NH3)4 ]2+...Ch. 21 - Prob. 66RQCh. 21 - Prob. 67RQCh. 21 - 21.68 The following compound is called...Ch. 21 - Prob. 69RQCh. 21 - Isomers of Metal Complexes
*21.70 Below is a...Ch. 21 - Prob. 71RQCh. 21 - Prob. 72RQCh. 21 - Prob. 73RQCh. 21 - Prob. 74RQCh. 21 - Bonding in Metal Complexes
*21.75 In which complex...Ch. 21 - Prob. 76RQCh. 21 - Prob. 77RQCh. 21 - Prob. 78RQCh. 21 - Prob. 79RQCh. 21 - Prob. 80RQCh. 21 - Referring to the two ligands, A and B, described...Ch. 21 - Referring to the complexes in Problems 21.80 and...Ch. 21 - Prob. 83RQCh. 21 - Prob. 84RQCh. 21 - *21.85 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.86 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.87 ions can be either four coordinate or six...Ch. 21 - Prob. 88RQCh. 21 - Most of the first row transition metals form 2+...Ch. 21 - *21.90 Is the complex chiral? Illustrate your...Ch. 21 - The complex [PtCl2(NH3)2] can be obtained as two...Ch. 21 - Prob. 92RQCh. 21 - Prob. 93RQCh. 21 - The compound Cr2(NH3)3(H2O)3Cl is a neutral salt...Ch. 21 - Prob. 95RQCh. 21 - Prob. 96RQCh. 21 - Prob. 97RQCh. 21 - Prob. 98RQCh. 21 - Prob. 99RQCh. 21 - Platinum(IV) makes compounds with coordination...Ch. 21 - Prob. 101RQCh. 21 - Prob. 102RQ
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 1. Draw the diastereoisomers of [Co(NH₃)₂(H₂O)₂Cl₂]⁺, if there's any. If there is none, upload a photo saying there are no diastereoisomers of the compound. 2. Draw the optical isomers of [Co(NH₃)₂(H₂O)₂Cl₂]⁺, if there's any. If there is none, upload a photo saying there are no optical isomers of the compound.arrow_forwardGive the total number of isomers with the formula [PtCl3Br3]2−. total isomers:arrow_forwardDraw and explain step by steparrow_forward
- In the following compounds, give the oxidation number of the metal center and represent the possible isomers. Indicating the type of isomerism involved. [CoCl2(H2N-CH2-CH2-NH2)2]arrow_forwardBased on the structures provided below, choose the incorrect statement. ethylene diamine (c) do op of to 2 3 Note: X and Y are monodentate ligands. Select one: ○ a. Structures 1 and 2 are optical isomers b. Structures 1 and 3 are optical isomers Structures 1 and 3 are geometric isomers О с. ○ d. Structures 2 and 4 are geometric isomers ○ e. Structures 3 and 4 are identicalarrow_forward[Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O Explain why the addition of water changes the equilibrium position even though the concentration of water is essentially constant and normally not included in the equilibrium constant expression. What are two functions that water performs in this reaction?arrow_forward
- Which molecule is chiral? A)[Fe(Phen)3]2+ B)HCl C)H2 D)CH4arrow_forwardIndicate how many stereoisomers are possible for each compound. square planar [Pt (NH₂)₂Cl₂]: tetrahedral [NiCl₂Br]²¯: octahedral [Fe (CO) 4C1₂]: stereoisomer(s) stereoisomer(s) stereoisomer(s)arrow_forwardWhich of the following compounds is chiral?arrow_forward
- How is ligand bound to a protein? List the physical forces?arrow_forwardCorrect statement(s) is/are regarding the compounds given in the figure?arrow_forwardGiven the compound: [Co(en)2(OH)2]OH, what type of stereoisomers can form? geometric and optical neither optical only geometric onlyarrow_forward
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