The IUPAC names of the given coordination complexes are to be determined Concept Information: Complex ions are the ions that are formed when a metal atom is at the center and other non-metallic molecules or ions surround it. Ligands are the molecules or ions that are bonded to a metal ion with a coordinate covalent bond. Coordination complexes are the complexes formed through coordinate covalent bonds between ligands and metals. Usually, in IUPAC nomenclature , the name of a neutral ligand does not change when naming a coordination complex, but water and ammonia are exceptions and their names change to aqua and ammine, respectively. Anionic ligands change their name when naming a coordination complex, based on the suffix in their names. The ligands ending with – ide change to the suffix – o, those ending with – ite change to the suffix – ito, and the ligands ending with – ate change to the suffix – ato. For naming a metallic ion, if the complex is anionic, then the name of the central metal ion in the coordinate complex ends with the suffix –ate and for neutral and cationic complexes, no changes are made to the name. The oxidation state of the metal is indicated by the roman numeral within the parenthesis following, without any space, the name of the metal.

Question

Want to see the full answer?

Answer 1

Question

Chapter 21, Problem 60RQ

Interpretation Introduction

Interpretation:

The IUPAC names of the given coordination complexes are to be determined

Concept Information:

Complex ions are the ions that are formed when a metal atom is at the center and other non-metallic molecules or ions surround it.

Ligands are the molecules or ions that are bonded to a metal ion with a coordinate covalent bond.

Coordination complexes are the complexes formed through coordinate covalent bonds between ligands and metals.

Usually, in IUPAC nomenclature, the name of a neutral ligand does not change when naming a coordination complex, but water and ammonia are exceptions and their names change to aqua and ammine, respectively.

Anionic ligands change their name when naming a coordination complex, based on the suffix in their names. The ligands ending with –ide change to the suffix –o, those ending with –ite change to the suffix –ito, and the ligands ending with –ate change to the suffix –ato.

For naming a metallic ion, if the complex is anionic, then the name of the central metal ion in the coordinate complex ends with the suffix –ate and for neutral and cationic complexes, no changes are made to the name. The oxidation state of the metal is indicated by the roman numeral within the parenthesis following, without any space, the name of the metal.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Predict the product of the reaction below (3 pts). hydrazine Ph H₂NNH2 KOH Write the mechanism for the above reaction using curved arrows to show electron movements. show all intermediates in the process (7 pts).

↓ Feedback (8/10) Draw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 2 attempts remaining N H3O+ 0 × Select to Draw + V Retry

2. Calculate the branching ratio of the reaction of the methyl peroxy radical with either HO, NO 298K) (note: rate constant can be found in the tropospheric chemistry ppt CH,O,+NO-HCHO+HO, + NO, CH₂O+HO, CH₂00H +0₂ when the concentration of hydroperoxyl radical is DH01-1.5 x 10 molecules and the nitrogen oxide maxing ratio of 10 ppb when the concentration of hydroperoxyl radicalis [H0] +1.5x10 molecules cm" and the nitrogen oxide mixing ratio of 30 p Under which condition do you expect more formaldehyde to be produced and why