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a)
Interpretation:
The IUPAC name of the compound represented by the model shown is to be given.
Concept introduction:
The names of simple carboxylic acids which are derivatives of open-chain
To give:
The IUPAC name of the compound represented by the model shown.
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Answer to Problem 17VC
The IUPAC name is 3-bromo-4-methoxybenzoic acid.
Explanation of Solution
The compound represented by the model is
It is a benzoic acid derivative with a bromine atom on C3 and a methoxyl group on C4.
The IUPAC name of the compound represented by the model shown is 3-bromo-4-methoxybenzoic acid.
b)
Interpretation:
The IUPAC name of the compound represented by the model shown is to be given.
Concept introduction:
The names of simple carboxylic acids which are derivatives of open-chain alkanes are arrived by replacing the terminal –e of the corresponding alkane name by –oic acid. The numbering starts from carboxyl carbon. Compounds with –COOH bonded to a ring are named using the suffix-carboxylic acid. The –COOH carbon in this case is not numbered as C1, instead the carbon to which it is attached is numbered as C1. As a substituent, the –COOH group is called as carboxyl group.
To give:
The IUPAC name of the compound represented by the model shown.
![Check Mark](/static/check-mark.png)
Answer to Problem 17VC
The IUPAC name of the compound represented by the model shown is 3-methyl-2-butenoic acid.
Explanation of Solution
The compound represented by the model is
The compound is an unsaturated acid having a four carbon straight chain with a double bond between C2 and C3.
The IUPAC name of the compound represented by the model shown is 3-methyl-2-butenoic acid.
c)
Interpretation:
The IUPAC name of the compound represented by the model shown is to be given.
Concept introduction:
The names of simple carboxylic acids which are derivatives of open-chain alkanes are arrived by replacing the terminal –e of the corresponding alkane name by –oic acid. The numbering starts from carboxyl carbon. Compounds with –COOH bonded to a ring are named using the suffix-carboxylic acid. The –COOH carbon in this case is not numbered as C1, instead the carbon to which it is attached is numbered as C1. As a substituent, the –COOH group is called as carboxyl group.
To give:
The IUPAC name of the compound represented by the model shown.
![Check Mark](/static/check-mark.png)
Answer to Problem 17VC
The IUPAC name of the compound represented by the model shown is cyclopenta-1,3-dienecarboxylic acid.
Explanation of Solution
The compound represented by the model is
The compound has a cyclopentadiene ring to which a carboxyl group is attached. The double bonds in the diene are in between C1 & C2 and C3 & C4.
The IUPAC name of the compound represented by the model shown is cyclopenta-1,3-dienecarboxylic acid.
d)
Interpretation:
The IUPAC name of the compound represented by the model shown is to be given.
Concept introduction:
The names of simple carboxylic acids which are derivatives of open-chain alkanes are arrived by replacing the terminal –e of the corresponding alkane name by –oic acid. The numbering starts from carboxyl carbon. Compounds with –COOH bonded to a ring are named using the suffix-carboxylic acid. The –COOH carbon in this case is not numbered as C1, instead the carbon to which it is attached is numbered as C1. As a substituent, the –COOH group is called as carboxyl group.
To give:
The IUPAC name of the compound represented by the model shown.
![Check Mark](/static/check-mark.png)
Answer to Problem 17VC
The IUPAC name of the compound represented by the model shown is (S)-3-cyclopentyl-2-methylpropanoic acid.
Explanation of Solution
The compound represented by the model is
The compound is a carboxylic acid with a three carbon straight chin and has a methyl group attached to C2 and cyclopentyl group attached to C3. The compound is optically active as C2 is chiral. The groups of first highest, second highest and third highest groups when viewed away from the group of last priority are arranged in the anti-clockwise direction. Hence the compound has S stereochemistry.
The IUPAC name of the compound represented by the model shown is (S)-3-cyclopentyl-2-methylpropanoic acid.
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Chapter 20 Solutions
OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card for McMurry's Organic Chemistry, 9th
- NH2 1. CH3–MgCl 2. H3O+ ? As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C - C bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new C - C bond. Х ☐: Carrow_forwardPredict the major products of this organic reaction. If there will be no major products, check the box under the drawing area instead. No reaction. : + Х è OH K Cr O 2 27 2 4' 2 Click and drag to start drawing a structure.arrow_forwardLaminar compounds are characterized by havinga) a high value of the internal surface of the solid.b) a high adsorption potential.arrow_forward
- Intercalation compounds have their sheetsa) negatively charged.b) positively charged.arrow_forwardIndicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/garrow_forwardIndicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
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