ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 20.12, Problem 19P
Interpretation Introduction

Interpretation:

The resonance contributing structure of the thymine is to be drawn. The evidence that supports the statement that the thymine follows the Hückel’s rule is to be explained.

Concept introduction:

A molecule that is cyclic, planar, completely conjugated and follows Huckel’s rule is classified as an aromatic compound.

Aromatic compounds follow Huckel’s rule of (4n+2)π electrons.

A ring that contains six or ten π electrons acts as an aromatic ring.

The stability of a compound depends upon the number of resonating structures.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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