(a)
Interpretation: The oxidation state of iron and its electronic configuration in
Concept introduction: Electronic configuration is used to describe the distribution of the electrons in the orbitals of an atom. Structure of an atom can be defined by its electronic configuration. It can also be used to denote an atom which is ionized to a cation or anion formed by the loss or gain of electrons in their respective orbitals.
To determine: The oxidation state of iron and its electronic configuration in
(b)
Interpretation: The oxidation state of iron and its electronic configuration in
Concept introduction: Electronic configuration is used to describe the distribution of the electrons in the orbitals of an atom. Structure of an atom can be defined by its electronic configuration. It can also be used to denote an atom which is ionized to a cation or anion formed by the loss or gain of electrons in their respective orbitals.
To determine: The volume of nitrogen gas that can be formed at
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Chemistry: An Atoms First Approach
- The ferrate ion, FeO42, is such a powerful oxidizing agent that in acidic solution, aqueous ammonia is reduced to elemental nitrogen along with the formation of the iron(III) ion. a. What is the oxidation state of iron in FeO42, and what is the electron configuration of iron in this polyatornic ion? b. lf 25.0 mL of a 0.243 M FeO42 solution is allowed to react with 55.0 mL of 1.45 M aqueous ammonia, what volume of nitrogen gas can form at 25C and 1.50 atm?arrow_forwardWhich of the following statements is not correct? (a) The ease of oxidation of the halide ions is F Cl Br I. (b) Fluorine is the most abundant halogen in the Earths crust. (c) F2 is prepared industrially by electrolysis of aqueous NaF. (d) HF is used to etch glass.arrow_forwardThe halogen oxides and oxoanions are good oxidizing agents. For example, the reduction of bromate ion has an E value of 1.44 V in acid solution: 2BrO3(aq)+12H+(aq)+10eBr2(aq)+6H2O(l) Is it possible to oxidize aqueous 1.0 M Mn2+ to aqueous MnO4 with 1.0 M bromate ion?arrow_forward
- Determine the oxidation state of sulfur in SF6, SO2F2, and KHS.arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?arrow_forwardThree reactions very important to the semiconductor industry are The reduction of silicon dioxide to crude silicon, SiO2(s) + 2 C(s) → Si(s) + 2 CO(g) ΔrH° = 689.9 kJ/mol The formation of silicon tetrachloride from crude silicon, Si(s) + 2 Cl2(g) → SiCl4(g) ΔrH° = −657.01 kJ/mol The reduction of silicon tetrachloride to pure silicon with magnesium, SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔrH° = −625.6 kJ/mol Calculate the overall enthalpy change when 1.00 mol sand, SiO2, changes into very pure silicon by this series of reactions.arrow_forward
- An aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?arrow_forwardThe Ostwald process for the commercial production of nitric acid involves the Following three steps: 4NH3(g)+5O2(g)4NO(g)+6H2O(s)2NO(g)+O2(g)2NO2(g)3NO2(g)+H2O(l)2HNO3(aq)+NO(g) a. Which reaction in the Ostwald process are oxidation-reduction reactions? b. Identify each oxidizing agent and reducing agent.arrow_forwardElectrolysis of an alkaline earth metal chloride using a current of 5.00 A for 748 s deposits 0.471 g of metal at the cathode. What is the identity of the alkaline earth metal chloride?arrow_forward
- What is the oxidation state of the halogen in each of the following?. (a) H5IO6. (b) IO4-. (c) ClO2. (d) ICl3. (e) F2arrow_forwardCopper(I) ion disproportionates to copper metal and copper(ll) ion. (See Study Question 99.) 2 Cu+(aq) Cu(s) + Cu2 + (aq) (a) What two half-reactions make up the disproportionation reaction? (b) Use values of the standard reduction potentials for the two half-reactions in part (a) to determine whether this disproportionation reaction is product-favored at equilibrium. (c) What is the equilibrium constant for this reaction? If you have a solution that initially contains 0.10 mol of Cu+ in 1.0 L of water, what are the concentrations of Cu+ and Cu2+ at equilibrium?arrow_forward
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