Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 20, Problem 84CWP
Which of the following molecules exhibit(s) optical isomerism?
a. cis-Pt(NH3)2Cl2
b. trans-Ni(en)2Br2 (en is ethylenediamine)
c. cis-Ni(en)2Br2 (en is ethylenediamine)
d. 
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What is the formula for bromobis(ethylenediamine)vanadium(II) bromide?
a. [VBr3(en)2]
b. [VBr(en)2]Br
C. [VBr2(en)2]*
d. Br[VBr2(en)]
e. [VBr2(en)]Br2
18. Isomeric cobalt compounds [Co(NH3)$SO4]Br and [Co(NH3)sBr]SO4 are red and violet
respectively.
Which of the following is true for the compounds?
A. The oxidation number of cobalt is +2.
B. They have the same number of coordinate bonds.
C. They form white precipitate with barium chloride solution.
D. An alkaline gas is given off when heated with sodium hydroxide solution.
18. Isomeric cobalt compounds and [Co(NH3)sBr]SO4 are red and violet
respectively. Which of the following is true for the compounds? *
A. The oxidation number of cobalt is +2.
B. They have the same number of coordinate bonds.
C. They form white precipitate with barium chloride solution.
D. An alkaline gas is given off when heated with sodium hydroxide solution.
O A
Ов
Chapter 20 Solutions
Chemistry: An Atoms First Approach
Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - Prob. 4RQCh. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1ALQCh. 20 - Prob. 2ALQCh. 20 - Prob. 3ALQCh. 20 - Prob. 4ALQCh. 20 - Prob. 5QCh. 20 - Four different octahedral chromium coordination...Ch. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - Prob. 9QCh. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - Prob. 12QCh. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 15QCh. 20 - Prob. 16QCh. 20 - Prob. 17QCh. 20 - Prob. 18QCh. 20 - Prob. 19QCh. 20 - Prob. 20QCh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Prob. 27ECh. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - A coordination compound of cobalt(III) contains...Ch. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Give formulas for the following complex ions. a....Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Amino acids can act as ligands toward transition...Ch. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - The CrF64 ion is known to have four unpaired...Ch. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - The wavelength of absorbed electromagnetic...Ch. 20 - The complex ion NiCL42 has two unpaired electrons,...Ch. 20 - How many unpaired electrons are present in the...Ch. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Silver is sometimes found in nature as large...Ch. 20 - Prob. 70ECh. 20 - Prob. 71AECh. 20 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 20 - Prob. 73AECh. 20 - Prob. 74AECh. 20 - Prob. 75AECh. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Name the following coordination compounds. a....Ch. 20 - Prob. 79AECh. 20 - Prob. 80AECh. 20 - Carbon monoxide is toxic because it binds more...Ch. 20 - For the process Co(NH3)5Cl2++ClCO(NH3)4Cl2++NH3...Ch. 20 - Prob. 83CWPCh. 20 - Which of the following molecules exhibit(s)...Ch. 20 - Prob. 85CWPCh. 20 - Prob. 86CWPCh. 20 - Prob. 87CWPCh. 20 - Which of the following statement(s) is( are) true?...Ch. 20 - Prob. 89CPCh. 20 - Consider the pseudo-octahedral complex ion of...Ch. 20 - Prob. 91CPCh. 20 - Prob. 92CPCh. 20 - Prob. 93CPCh. 20 - Prob. 94CPCh. 20 - Prob. 95CPCh. 20 - Prob. 96CPCh. 20 - Prob. 97CPCh. 20 - Prob. 98IPCh. 20 - Prob. 99IPCh. 20 - Prob. 100IPCh. 20 - Prob. 101MP
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- Which of the following molecules exhibit(s) optical isomerism? a. cis-Pt(NH3)2Cl2 b. trans-Ni(en)2Br2 (en is ethylenediamine) c. cis-Ni(en)2Br2 (en is ethylenediamine) d.arrow_forwardWhat structural feature is used to determine whether a compound can exist as optical isomers?arrow_forwardDoes [Co(en)2Cl2]Cl exhibit geometrical isomerism? Yes Does it exhibit optical isomerism? Trans form – No Cis form – Yes Explain???arrow_forward
- D. Make Pt(H2O)2Br2Cl2. If this molecule has isomers (geometric and/or optical) draw all of them.arrow_forward- A compound has the empirical formula CoCl3 5NH3. One mole of it yields two moles of silver chloride when treated with silver nitrate. Ammonia is not removed by treatment with concentrated sulfuric acid. A reasonable formula for the compound is A. [Co(NH3);Ci]I2 B. [Co(NH3)s]CI; C. CoCl3-5NH3 D. [Co(NH3),Ci]CI2arrow_forwardWhich of the following forms of isomerism can be exhibited by [Ni(en)2Cl2]? Draw and label those that apply. A. cis-trans isomerism B. coordination isomerism C. linkage isomerism D. mer-fac isomerism E. optical isomerismarrow_forward
- Choose the correct statement about the isomers of [Pt(H2O)2(NH3)CI] Br. I H20 NH3 II H20 NH 3 Pd Pd C1 OH2 120 C1 Select one: O a. They are not isomers. O b. The two molecules are not optically active. O c. Iis cis, Il is trans. O d. The two molecules are the same. e. The two molecules are mirror images of each other.arrow_forward21. Name the following compounds. a. Ni(CO), b. Naz[Co(H;O)2(OH),] c. [Ag(NH3)2]Br d. [Co(NH,),CI]SO, g. [Ni(NH3).(H2O)2](NO3)2arrow_forwardDetermine the chemical formula for the compound, diamminetetraaquairon (II) chloride. Select one: O a. [Fe(NH3)2(H2O)4CI] b. [Fe(H20)4][(NH3)2CI] c. [Fe(NH3)2][(H2O)4CI] O d. [Fe(NH3)2(H2O)4]C12arrow_forward
- Which of the following species can exhibit geometric isomerism? a. [Co(en)2ClBr]+ b. [Cr(en)Cl2Br2]- c. [Pt(NH3)3Cl3]- d. [Pt(NH3)(en)Cl]+arrow_forwardChoose the letter of the correct answer from the choices given.arrow_forwardWhich of the following can be exhibited by [Ni(en)2Cl2]? Draw and label what applies. A. mer-fac isomerism B. optical isomerism C. coordination isomerism D. linkage isomerismarrow_forward
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