Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Question
Chapter 20, Problem 96CP
(a)
Interpretation Introduction
Interpretation: The d orbital diagram for a linear complex with ligands on the x axis and ligands on the y axis is to be drawn.
Concept introduction: The electrons in the d orbital of a
To determine: The d orbital diagram for a linear complex with ligands on the x axis.
(b)
Interpretation Introduction
Interpretation: The d orbital diagram for a linear complex with ligands on the x axis and ligands on the y axis is to be drawn.
Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
To determine: The d orbital diagram for a linear complex with ligands on the y axis.
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From the given compound, choose the proton that best fits each given description.
a
CH2
CH 2
Cl
b
с
CH2
F
Most shielded:
(Choose one)
Least shielded:
(Choose one)
Highest chemical shift:
(Choose one)
Lowest chemical shift:
(Choose one)
×
Consider this molecule:
How many H atoms are in this molecule?
How many different signals could be found in its 1H NMR spectrum?
Note: A multiplet is considered one signal.
For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither.
Compound
m/z of M* peak
m/z of M
+ 2 peak
ratio of M+ : M
+ 2 peak
Which element is present?
A
122
no M
+ 2 peak
not applicable
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B
78
80
3:1
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C
227
229
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Chapter 20 Solutions
Chemistry: An Atoms First Approach
Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - Prob. 4RQCh. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1ALQCh. 20 - Prob. 2ALQCh. 20 - Prob. 3ALQCh. 20 - Prob. 4ALQCh. 20 - Prob. 5QCh. 20 - Four different octahedral chromium coordination...Ch. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - Prob. 9QCh. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - Prob. 12QCh. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 15QCh. 20 - Prob. 16QCh. 20 - Prob. 17QCh. 20 - Prob. 18QCh. 20 - Prob. 19QCh. 20 - Prob. 20QCh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Prob. 27ECh. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - A coordination compound of cobalt(III) contains...Ch. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Give formulas for the following complex ions. a....Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Amino acids can act as ligands toward transition...Ch. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - The CrF64 ion is known to have four unpaired...Ch. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - The wavelength of absorbed electromagnetic...Ch. 20 - The complex ion NiCL42 has two unpaired electrons,...Ch. 20 - How many unpaired electrons are present in the...Ch. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Silver is sometimes found in nature as large...Ch. 20 - Prob. 70ECh. 20 - Prob. 71AECh. 20 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 20 - Prob. 73AECh. 20 - Prob. 74AECh. 20 - Prob. 75AECh. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Name the following coordination compounds. a....Ch. 20 - Prob. 79AECh. 20 - Prob. 80AECh. 20 - Carbon monoxide is toxic because it binds more...Ch. 20 - For the process Co(NH3)5Cl2++ClCO(NH3)4Cl2++NH3...Ch. 20 - Prob. 83CWPCh. 20 - Which of the following molecules exhibit(s)...Ch. 20 - Prob. 85CWPCh. 20 - Prob. 86CWPCh. 20 - Prob. 87CWPCh. 20 - Which of the following statement(s) is( are) true?...Ch. 20 - Prob. 89CPCh. 20 - Consider the pseudo-octahedral complex ion of...Ch. 20 - Prob. 91CPCh. 20 - Prob. 92CPCh. 20 - Prob. 93CPCh. 20 - Prob. 94CPCh. 20 - Prob. 95CPCh. 20 - Prob. 96CPCh. 20 - Prob. 97CPCh. 20 - Prob. 98IPCh. 20 - Prob. 99IPCh. 20 - Prob. 100IPCh. 20 - Prob. 101MP
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- Don't used hand raiting and don't used Ai solutionarrow_forward2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forward
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