Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 20, Problem 29E
Interpretation Introduction
Interpretation: It is given that, when
Concept introduction: In a balanced reaction, number of atoms is same on both sides of the chemical equation.
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A manganese complex formed from a solution containing potassium bromide and oxalate ion is purified and analyzed. It contains 10.0% Mn, 28.6% potassium, 8.8% carbon, and 29.2% bromine by mass. The remainder of the compound is oxygen. An aqueous solution of the complex has about the same electrical conductivity as an equimolar solution of K4[Fe(CN)6]. Write the formula of the compound, using brackets to denote the manganese and its coordination sphere.
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Chapter 20 Solutions
Chemistry: An Atoms First Approach
Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - Prob. 4RQCh. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1ALQCh. 20 - Prob. 2ALQCh. 20 - Prob. 3ALQCh. 20 - Prob. 4ALQCh. 20 - Prob. 5QCh. 20 - Four different octahedral chromium coordination...Ch. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - Prob. 9QCh. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - Prob. 12QCh. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 15QCh. 20 - Prob. 16QCh. 20 - Prob. 17QCh. 20 - Prob. 18QCh. 20 - Prob. 19QCh. 20 - Prob. 20QCh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Prob. 27ECh. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - A coordination compound of cobalt(III) contains...Ch. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Give formulas for the following complex ions. a....Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Amino acids can act as ligands toward transition...Ch. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - The CrF64 ion is known to have four unpaired...Ch. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - The wavelength of absorbed electromagnetic...Ch. 20 - The complex ion NiCL42 has two unpaired electrons,...Ch. 20 - How many unpaired electrons are present in the...Ch. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Silver is sometimes found in nature as large...Ch. 20 - Prob. 70ECh. 20 - Prob. 71AECh. 20 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 20 - Prob. 73AECh. 20 - Prob. 74AECh. 20 - Prob. 75AECh. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Name the following coordination compounds. a....Ch. 20 - Prob. 79AECh. 20 - Prob. 80AECh. 20 - Carbon monoxide is toxic because it binds more...Ch. 20 - For the process Co(NH3)5Cl2++ClCO(NH3)4Cl2++NH3...Ch. 20 - Prob. 83CWPCh. 20 - Which of the following molecules exhibit(s)...Ch. 20 - Prob. 85CWPCh. 20 - Prob. 86CWPCh. 20 - Prob. 87CWPCh. 20 - Which of the following statement(s) is( are) true?...Ch. 20 - Prob. 89CPCh. 20 - Consider the pseudo-octahedral complex ion of...Ch. 20 - Prob. 91CPCh. 20 - Prob. 92CPCh. 20 - Prob. 93CPCh. 20 - Prob. 94CPCh. 20 - Prob. 95CPCh. 20 - Prob. 96CPCh. 20 - Prob. 97CPCh. 20 - Prob. 98IPCh. 20 - Prob. 99IPCh. 20 - Prob. 100IPCh. 20 - Prob. 101MP
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- Write the formula and draw the structure of cis-tetraamminedichlorocobalt(III).arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forward(a) Draw a Lewis dot and cross structure (including any lone pairs) for a NBr3 molecule and determine the shape of the molecule and number of valence electrons. (b) Six ammonia ligands form a complex ion with Co²+. What is the overall charge of the complex ion? Write the formula for the complex ion. What is the coordination number of the complex ion? Explain how ammonia ligands form a complex ion with Co²+? What is the geometry of the complex ion? Would you expect the complex to be coloured? Explain why? i. ii. iii. iv. V. vi.arrow_forward
- Metal cations often form complex ions in solution or when reacted with suitable ligands. Write a balanced equation for the formation of Cu(en)22+ from Cu2+ and ethylenediamine (en) in an aqueous solution.arrow_forward1. A sample of iron ore weighing 0.6428 g is dissolved in acid The iron is reduced to Fe* and titrated with 36.30 mL of a 0.1052 N solution of K,Cr207. (a) Calculate the percentage of iron (Fe) in the sample. (b) Express the percentage as Fe,03 rather than Fe. Hint: The reaction of Fe2+ with Cr,0,2 involves one electron to oxidize it to Fe*.arrow_forwardA concentrated ammonia solution is added to a 0.010 M Ni(No3)2 to solution. Given the equilibrium concentration of ammonia [NH3] to is 0.20 M, determine the nickel (II) ion concentration. The formation constant Kf of the complex Ni(NH3)6^2+ + is 1.2 x 10^9. Assume the volume change from the addition of ammonia solution is negligible.[No^2+]=arrow_forward
- Which is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+arrow_forwardWhy do Selenium and tellurium occur in rare minerals?arrow_forwardMany transition metals and their compounds are used as catalysts. Given MnO2, FeCl3, Pt, and Ni, which would you select for producing CCl4 from CS2 and Cl2?arrow_forward
- [Fe(H2O)6]3+ (aq) + SCN1- ↔ Fe(H2O)5SCN]2+(aq) + heat yellow red For the above reaction, describe using Le Chatelier’s Principle what changes (color changes and shifts) would occur when each stress is applied to this equilibrium. Explain your answers. a) Add KSCN(aq) b) Decrease temperature c) Add AgNO3, which causes AgSCN to precipitate out.arrow_forwardUsing crystal field theory, draw an electron box energy level diagram for the valence d orbitals on the iron atom in a tetrahedral FeCl, complex. Your diagram should show the relative energy of each orbital, and the number of electrons in each orbital. Note: to make your diagram easier to read, label the d orbitals with just the subscript. For example, label the d 2 orbital with just z. Energyarrow_forwardSome metal complexes have a coordination number of 5. One such complex is Fe(CO)5, which adopts a trigonal bipyramidal geometry. What is the oxidation state of Fe in this compound?arrow_forward
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