Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 20, Problem 48QAP
Interpretation Introduction

Interpretation:

The structural formulas showing all possible molecules containing six carbon atoms with one triple bond should be determined.

Concept Introduction:

For six carbons and one triple bond, isomers are mainly hexyne and pentyne with alkyl side groups.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 20 Solutions

Introductory Chemistry: A Foundation

Ch. 20 - Prob. 3ALQCh. 20 - How many different possible “tetramethylbenzenes”...Ch. 20 - For the general formula C6H14O, draw the...Ch. 20 - Prob. 6ALQCh. 20 - Prob. 1QAPCh. 20 - Your roommate, a chemistry major, claims to have...Ch. 20 - Prob. 3QAPCh. 20 - How many electron pairs are shared when a triple...Ch. 20 - Prob. 5QAPCh. 20 - Prob. 6QAPCh. 20 - Prob. 7QAPCh. 20 - Prob. 8QAPCh. 20 - Prob. 9QAPCh. 20 - . The chains in normal alkanes are not really...Ch. 20 - Prob. 11QAPCh. 20 - Prob. 12QAPCh. 20 - . Give the name of each of the following...Ch. 20 - Prob. 14QAPCh. 20 - . What are structural isomers? Which is the...Ch. 20 - Prob. 16QAPCh. 20 - Prob. 17QAPCh. 20 - Prob. 18QAPCh. 20 - Prob. 19QAPCh. 20 - Prob. 20QAPCh. 20 - . What is an alkyl group? How is a given alkyl...Ch. 20 - Prob. 22QAPCh. 20 - Prob. 23QAPCh. 20 - Prob. 24QAPCh. 20 - . Give the systematic name for each of the...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 27QAPCh. 20 - Prob. 28QAPCh. 20 - Prob. 29QAPCh. 20 - Prob. 30QAPCh. 20 - . What is pyrolytic cracking, and why is the...Ch. 20 - Prob. 32QAPCh. 20 - . Explain why alkanes are relatively unreactive.Ch. 20 - Prob. 34QAPCh. 20 - . Indicate the missing molecule in each of the...Ch. 20 - Prob. 36QAPCh. 20 - Prob. 37QAPCh. 20 - Prob. 38QAPCh. 20 - Prob. 39QAPCh. 20 - Prob. 40QAPCh. 20 - Prob. 41QAPCh. 20 - Prob. 42QAPCh. 20 - Prob. 43QAPCh. 20 - Prob. 44QAPCh. 20 - Prob. 45QAPCh. 20 - Prob. 46QAPCh. 20 - Prob. 47QAPCh. 20 - Prob. 48QAPCh. 20 - Prob. 49QAPCh. 20 - . Benzene exhibits resonance Explain this...Ch. 20 - . How is a monosubstituted benzene named? Give the...Ch. 20 - Prob. 52QAPCh. 20 - Prob. 53QAPCh. 20 - . What do the prefixes ortho-, meta-, and para-...Ch. 20 - Prob. 55QAPCh. 20 - Prob. 56QAPCh. 20 - Prob. 57QAPCh. 20 - Prob. 58QAPCh. 20 - . What functional group characterizes an alcohol?...Ch. 20 - Prob. 60QAPCh. 20 - . Give the systematic name for each of the...Ch. 20 - Without looking back at the text, draw the...Ch. 20 - . Why is methanol sometimes called wood alcohol?...Ch. 20 - Prob. 64QAPCh. 20 - . Write the equation for the synthesis of ethanol...Ch. 20 - Prob. 66QAPCh. 20 - Prob. 67QAPCh. 20 - Prob. 68QAPCh. 20 - Prob. 69QAPCh. 20 - Prob. 70QAPCh. 20 - Prob. 71QAPCh. 20 - Prob. 72QAPCh. 20 - Prob. 73QAPCh. 20 - Prob. 74QAPCh. 20 - Prob. 75QAPCh. 20 - Prob. 76QAPCh. 20 - Prob. 77QAPCh. 20 - Prob. 78QAPCh. 20 - Prob. 79QAPCh. 20 - Prob. 80QAPCh. 20 - Prob. 81QAPCh. 20 - . Draw a structural formula for each of the...Ch. 20 - Prob. 83QAPCh. 20 - Prob. 84QAPCh. 20 - Prob. 85QAPCh. 20 - Prob. 86QAPCh. 20 - Prob. 87QAPCh. 20 - Prob. 88QAPCh. 20 - Prob. 89APCh. 20 - Prob. 90APCh. 20 - Prob. 91APCh. 20 - Prob. 92APCh. 20 - Prob. 93APCh. 20 - . The systematic names of all saturated...Ch. 20 - Prob. 95APCh. 20 - Prob. 96APCh. 20 - Prob. 97APCh. 20 - Prob. 98APCh. 20 - Prob. 99APCh. 20 - . With very reactive agents, such as the halogen...Ch. 20 - . Alkenes and alkynes are characterized by their...Ch. 20 - Prob. 102APCh. 20 - Prob. 103APCh. 20 - Prob. 104APCh. 20 - Prob. 105APCh. 20 - Prob. 106APCh. 20 - Prob. 107APCh. 20 - Prob. 108APCh. 20 - Prob. 109APCh. 20 - Prob. 110APCh. 20 - Prob. 111APCh. 20 - Prob. 112APCh. 20 - Prob. 113APCh. 20 - Prob. 114APCh. 20 - Prob. 115APCh. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 117APCh. 20 - Prob. 118APCh. 20 - Prob. 119APCh. 20 - Prob. 120APCh. 20 - Prob. 121APCh. 20 - Prob. 122APCh. 20 - Prob. 123APCh. 20 - Prob. 124APCh. 20 - Prob. 125APCh. 20 - Prob. 126APCh. 20 - Prob. 127APCh. 20 - Prob. 128APCh. 20 - Prob. 129APCh. 20 - Prob. 130APCh. 20 - Prob. 131APCh. 20 - . Write the formula for the missing reactant or...Ch. 20 - Prob. 133APCh. 20 - Prob. 134APCh. 20 - . Name each of the following aromatic or...Ch. 20 - Prob. 136APCh. 20 - Prob. 137APCh. 20 - Prob. 138APCh. 20 - Prob. 139APCh. 20 - Prob. 140APCh. 20 - Prob. 141APCh. 20 - . Name each of the following alkanes....Ch. 20 - Prob. 143CPCh. 20 - Prob. 144CPCh. 20 - Prob. 145CPCh. 20 - Prob. 146CPCh. 20 - Prob. 147CP
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