(a) Interpretation: The hemiacetal Carbon ** the −OH group in the hemiacetal Carbon should be identified. Concept introduction: When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

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Answer 1

Question

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.

Answer 2

Question

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

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Answer 3

Question

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Expert Solution & Answer

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Answer 4

Question

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

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Answer 5

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Answer 6

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Answer 7

Chapter 20, Problem 36P

Interpretation Introduction

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The 4 Hydroxyl groups (apart from the anomeric hydroxyl group) should be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Concept introduction:

Depending on the no. of Hydrogen atoms attached to the Carbon atom with hydroxyl group (-OH), they can be classified as primary (1 °), secondary (2 °) & tertiary (3 °) hydroxyls.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 20.1 - Label the hemiacetal carbonthe carbon bonded to...Ch. 20.2 - Prob. 20.1PP Ch. 20.2 - Prob. 20.2P Ch. 20.2 - Prob. 20.3P Ch. 20.2 - Prob. 20.4P Ch. 20.2 - Prob. 20.5P Ch. 20.2 - Prob. 20.2PP Ch. 20.2 - Prob. 20.6P Ch. 20.2 - Prob. 20.7P Ch. 20.3 - Prob. 20.8P

(a) Interpretation: The hemiacetal Carbon ** the −OH group in the hemiacetal Carbon should be identified. Concept introduction: When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

Solution Summary: The author explains that the hemiacetal carbon and the anomeric carbon should be identified.

Concept explainers

(a)

Interpretation:

The hemiacetal Carbon the −OH group in the hemiacetal Carbon should be identified.

Concept introduction:**

When an alcohol and ether group are attached to the same carbon, it is called the hemiacetal carbon.The anomeric carbon is the carbon bearing the carbonyl group.

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Chapter 20 Solutions