Many gas-phase reactions require some inert body, usually represented as M , to absorb or supply energy in a collision in order to proceed. In the spontaneous decomposition of ozone, O 3 , we can suggest the mechanism O 3 + M → O 3 * + M O 3 * → RDS O 2 + ⋅ O ⋅ ⋅ O ⋅ + O 3 → 2 O 2 for the overall reaction 2O 3 → 3O 2 In the mechanism, O 3 * refers to an ozone molecule in some energetically excited state that can react spontaneously to form O 2 and O atoms. Determine the rate law of the proposed mechanism in terms of O 3 and M , where the second step is the rate-determining step. Will adding an inert gas like Ar to a sample of ozone increase or decrease the rate of the reaction ?
Many gas-phase reactions require some inert body, usually represented as M , to absorb or supply energy in a collision in order to proceed. In the spontaneous decomposition of ozone, O 3 , we can suggest the mechanism O 3 + M → O 3 * + M O 3 * → RDS O 2 + ⋅ O ⋅ ⋅ O ⋅ + O 3 → 2 O 2 for the overall reaction 2O 3 → 3O 2 In the mechanism, O 3 * refers to an ozone molecule in some energetically excited state that can react spontaneously to form O 2 and O atoms. Determine the rate law of the proposed mechanism in terms of O 3 and M , where the second step is the rate-determining step. Will adding an inert gas like Ar to a sample of ozone increase or decrease the rate of the reaction ?
Solution Summary: The author explains that the rate of a reaction depends on several factors such as the concentration of the reactant and temperature.
Many gas-phase reactions require some inert body, usually represented as
M
, to absorb or supply energy in a collision in order to proceed. In the spontaneous decomposition of ozone,
O
3
, we can suggest the mechanism
O
3
+
M
→
O
3
*
+
M
O
3
*
→
RDS
O
2
+
⋅
O
⋅
⋅
O
⋅
+
O
3
→
2
O
2
for the overall reaction
2O
3
→
3O
2
In the mechanism,
O
3
*
refers to an ozone molecule in some energetically excited state that can react spontaneously to form
O
2
and
O
atoms. Determine the rate law of the proposed mechanism in terms of
O
3
and
M
, where the second step is the rate-determining step. Will adding an inert gas like
Ar
to a sample of ozone increase or decrease the rate of the reaction?
Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.
Write the amididation reaction mechanism of a-aminophenol and acetic acid to produce acetaminophen
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Chapter 20 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
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