The rate law for the reaction C 6 H 5 OH + HNO 2 → [ OH − catalyst ] C 6 H 5 NO 2 + H 2 O is rate = k [ C 6 H 5 OH ] [ HNO 2 ] At 35.0 ° C , k = 7.04 × 10 − 3 M − 1 s − 1 . If [ C 6 H 5 OH ] = 0.0433 M and [ HNO 2 ] = 6.05 M , what is the pseudo first-order rate law and what is the value of k ' ?
The rate law for the reaction C 6 H 5 OH + HNO 2 → [ OH − catalyst ] C 6 H 5 NO 2 + H 2 O is rate = k [ C 6 H 5 OH ] [ HNO 2 ] At 35.0 ° C , k = 7.04 × 10 − 3 M − 1 s − 1 . If [ C 6 H 5 OH ] = 0.0433 M and [ HNO 2 ] = 6.05 M , what is the pseudo first-order rate law and what is the value of k ' ?
Solution Summary: The author explains the pseudo-first-order rate law of the given reaction and the value of k'.
C
6
H
5
OH
+
HNO
2
→
[
OH
−
catalyst
]
C
6
H
5
NO
2
+
H
2
O
is
rate
=
k
[
C
6
H
5
OH
]
[
HNO
2
]
At
35.0
°
C
,
k
=
7.04
×
10
−
3
M
−
1
s
−
1
. If
[
C
6
H
5
OH
]
=
0.0433
M
and
[
HNO
2
]
=
6.05
M
, what is the pseudo first-order rate law and what is the value of
k
'
?
Using the following two half-reactions, determine the pH range in which $NO_2^-\ (aq)$ cannot be found as the predominant chemical species in water.* $NO_3^-(aq)+10H^+(aq)+8e^-\rightarrow NH_4^+(aq)+3H_2O(l),\ pE^{\circ}=14.88$* $NO_2^-(aq)+8H^+(aq)+6e^-\rightarrow NH_4^+(aq)+2H_2O(l),\ pE^{\circ}=15.08$
Indicate characteristics of oxodec acid.
What is the final product when hexanedioic acid reacts with 1º PCl5 and 2º NH3.
Chapter 20 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
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