A proposed mechanism for the gas-phase chlorination of methane is Cl 2 + CH 4 → CH 4 Cl + Cl ⋅ CH 4 Cl → CH 3 ⋅ + HCl CH 3 ⋅ + Cl 2 → CH 3 Cl + Cl ⋅ Cl ⋅ + CH 4 → CH 3 ⋅ + HCl Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants, Cl 2 and CH 4 ? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
A proposed mechanism for the gas-phase chlorination of methane is Cl 2 + CH 4 → CH 4 Cl + Cl ⋅ CH 4 Cl → CH 3 ⋅ + HCl CH 3 ⋅ + Cl 2 → CH 3 Cl + Cl ⋅ Cl ⋅ + CH 4 → CH 3 ⋅ + HCl Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants, Cl 2 and CH 4 ? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
Solution Summary: The author explains that the expected rate law for the chlorination of methane is to be determined. The rate of reaction depends on several factors such as the concentration of reactant and temperature.
Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants,
Cl
2
and
CH
4
? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
The rate constant for the decay of a radioactive element is 2.28 × 10⁻³ day⁻¹. What is the half-life of this element in days?
Handwritten please
Choose the best reagents to
complete the following
reaction.
i
H
A
B
1. CH3CH2Na
2. H3O+
1.
CH3CH2MgBr
2. H3O+
1. CH3MgBr
Q
C
2. H3O+
1. H3O+
D
2. CH3MgBr
00
OH
Q
E
CH³MgBr
Chapter 20 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
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