EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
6th Edition
ISBN: 9781319385415
Author: PARISE
Publisher: VST
Question
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Chapter 20, Problem 20.48AP
Interpretation Introduction

(a)

Interpretation:

The structures of the two separable products obtained on the decarboxylation of compound A are to be drawn.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the elimination of COOH group. The decarboxylation of the carboxylic acid can be done on heating the acid.

Interpretation Introduction

(b)

Interpretation:

The number of products obtained on the decarboxylation of compound B is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the elimination of COOH group. The decarboxylation of the carboxylic acid can be done on heating the acid.

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From the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×
Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.
For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)
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