The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions. Concept Introduction: Allylic systems: The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here: Stability of the allylic carbocations: Primary < Secondary < tertiary Example for Primary allylic carbocation is: Example for Secondary allylic carbocation is: Example for tertiary allylic carbocation is:

Question

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Answer 1

Question

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

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Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टे

Answer 2

Question

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

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Answer 3

Question

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

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Answer 4

Question

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Expert Solution & Answer

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Answer 5

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 6

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 7

Chapter 20, Problem 20.15P

(a)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 8

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 9

(b)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 10

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 11

(c)

Interpretation Introduction

Interpretation: The important resonance hybrids for the given allylic carbocations have to be drawn and ranked based on their contributions.

Concept Introduction:

Allylic systems:

The allylic system is characterized by the connectivity of a single bonded carbon atom connected to double bond alkene functional group as shown here:

Stability of the allylic carbocations:

Primary < Secondary < tertiary

Example for Primary allylic carbocation is:

Example for Secondary allylic carbocation is:

Example for tertiary allylic carbocation is:

Answer 12

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Answer 23

Ch. 20.1 - Prob. 20.1P Ch. 20.1 - Estimate the stabilization gained as a result of...Ch. 20.2 - Predict the product(s) formed by addition of one...Ch. 20.3 - Prob. 20.4P Ch. 20.3 - Prob. 20.5P Ch. 20.4 - Prob. 20.6P Ch. 20.5 - Prob. 20.7P Ch. 20.5 - Prob. 20.8P Ch. 20.5 - Prob. 20.9P Ch. 20.6 - Prob. 20.10P

Solution Summary: The author explains that the resonance hybrids for the given allylic carbocation have to be drawn based on their contributions.

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Chapter 20 Solutions