The sign ΔS sys for process that pond freezes in winter has to be determined. Concept introduction: Entropy change: The sign of ΔS o for a reaction is determined by using the following rules: When a molecule is broken down and gives two or more smaller molecules. When the moles of gas is increases (by the breaking of molecules) Solid changes to liquid or gas state or liquid state changes to gas state. Entropy ( S ) : it is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state. If the disorder increases in a system, then Δ S > 0 positive If the disorder decreases in a system, then Δ S < 0 negative If the disorder equal in a system, then Δ S = 0
The sign ΔS sys for process that pond freezes in winter has to be determined. Concept introduction: Entropy change: The sign of ΔS o for a reaction is determined by using the following rules: When a molecule is broken down and gives two or more smaller molecules. When the moles of gas is increases (by the breaking of molecules) Solid changes to liquid or gas state or liquid state changes to gas state. Entropy ( S ) : it is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state. If the disorder increases in a system, then Δ S > 0 positive If the disorder decreases in a system, then Δ S < 0 negative If the disorder equal in a system, then Δ S = 0
Definition Definition Substance that constitutes everything in the universe. Matter consists of atoms, which are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction: solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).
Chapter 20, Problem 20.15P
(a)
Interpretation Introduction
Interpretation:
The sign ΔSsys for process that pond freezes in winter has to be determined.
Concept introduction:
Entropy change:
The sign of ΔSo for a reaction is determined by using the following rules:
When a molecule is broken down and gives two or more smaller molecules.
When the moles of gas is increases (by the breaking of molecules)
Solid changes to liquid or gas state or liquid state changes to gas state.
Entropy(S): it is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.
If the disorder increases in a system, then ΔS>0 positive
If the disorder decreases in a system, then ΔS<0 negative
If the disorder equal in a system, then ΔS=0
(b)
Interpretation Introduction
Interpretation:
The sign ΔSsys for process atmospheric carbon dioxide dissolves in ocean has to be determined.
Concept introduction:
Entropy change:
The sign of ΔSo for a reaction is determined by using the following rules:
When a molecule is broken down and gives two or more smaller molecules.
When the moles of gas is increases (by the breaking of molecules)
Solid changes to liquid or gas state or liquid state changes to gas state.
Entropy(S): it is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.
If the disorder increases in a system, then ΔS>0 positive
If the disorder decreases in a system, then ΔS<0 negative
If the disorder equal in a system, then ΔS=0
(c)
Interpretation Introduction
Interpretation:
The sign ΔSsys for process an apple tree bears fruit has to be determined.
Concept introduction:
Entropy change:
The sign of ΔSo for a reaction is determined by using the following rules:
When a molecule is broken down and gives two or more smaller molecules.
When the moles of gas is increases (by the breaking of molecules)
Solid changes to liquid or gas state or liquid state changes to gas state.
Entropy(S): it is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.
If the disorder increases in a system, then ΔS>0 positive
If the disorder decreases in a system, then ΔS<0 negative
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY