Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Question
Chapter 20, Problem 20.11P
Interpretation Introduction
(a)
Interpretation: The structures for both, an acid chloride and an ester that can be used to prepare given compound by reduction are to be drawn.
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in
Interpretation Introduction
(b)
Interpretation: The structures for both, an acid chloride and an ester that can be used to prepare given compound by reduction are to be drawn.
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of acyl chlorides to primary alcohols.
Interpretation Introduction
(c)
Interpretation: The structures for both, an acid chloride and an ester that can be used to prepare given compound by reduction are to be drawn.
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of acyl chlorides to primary alcohols.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Calculate Kc for the reaction: I2 (g) ⇋ 2 I (g) Kp = 6.26 x 10-22 at 298K
For each scenario below, select the color of the solution using the indicator thymol blue during the titration.
When you first add indicator to your Na2CO3solution, the solution is basic (pH ~10), and the color is ["", "", "", "", ""] .
At the equivalence point for the titration, the moles of added HCl are equal to the moles of Na2CO3. One drop (or less!) past this is called the endpoint. The added HCl begins to titrate the thymol blue indicator itself. At the endpoint, the indicator color is ["", "", "", "", ""] .
When you weren't paying attention and added too much HCl (~12 mL extra), the color is ["", "", "", "", ""] .
When you really weren't paying attention and reached the second equivalence point of Na2CO3, the color is
To convert cyclopentane-CH2-CHO to cyclopentane-CH2-CH3, compound A is added, followed by (CH3)3CO-K+, DMS at 100oC. Indicate which compound A is.
Chapter 20 Solutions
Organic Chemistry
Ch. 20 - Prob. 20.1PCh. 20 - Which carbonyl groups in the anticancer drug taxol...Ch. 20 - Prob. 20.3PCh. 20 - Problem 20.4 What alcohol is formed when each...Ch. 20 - Problem 20.5 What aldehyde or ketone is needed to...Ch. 20 - Prob. 20.6PCh. 20 - Problem 20.7 Draw the products formed when is...Ch. 20 - Problem 20.8 Draw the products formed (including...Ch. 20 - Prob. 20.9PCh. 20 - Problem 20.10 Draw a stepwise mechanism for the...
Ch. 20 - Prob. 20.11PCh. 20 - Problem 20.12 Draw the products formed from ...Ch. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Problem-20.16 Review the oxidation reactions using...Ch. 20 - Problem-20.17 Write the step(s) needed to convert ...Ch. 20 - Problem-20.18 Oct-1-yne reacts rapidly with ,...Ch. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Problem 20.21 Draw the product of each reaction.
...Ch. 20 - Problem 20.22 Draw the products (including...Ch. 20 - Problem 20.23 What Grignard reagent and carbonyl...Ch. 20 - Problem 20.24 Linalool (the Chapter 9 opening...Ch. 20 - Problem 20.25 What Grignard reagent and carbonyl...Ch. 20 - Prob. 20.26PCh. 20 - Draw the products formed when each compound is...Ch. 20 - Problem 20.28 What ester and Grignard reagent are...Ch. 20 - Prob. 20.29PCh. 20 - Problem 20.30 What reagent is needed to convert ...Ch. 20 - Prob. 20.31PCh. 20 - What carboxylic acid formed from each alkyl halide...Ch. 20 - Prob. 20.33PCh. 20 - Problem 20.34 Draw the product when each compound...Ch. 20 - Problem 20.35 Synthesize each compound from...Ch. 20 - Prob. 20.36PCh. 20 - 20.37 Devise a synthesis of each alcohol from...Ch. 20 - 20.38 Draw the products formed when pentanal is...Ch. 20 - 20.39 Draw the product formed when is treated...Ch. 20 - The stereochemistry of the products of reduction...Ch. 20 - Prob. 20.41PCh. 20 - 20.42 Draw the products or each reduction...Ch. 20 - Prob. 20.43PCh. 20 - 20.44 Draw all stereoisomers formed in each...Ch. 20 - Prob. 20.45PCh. 20 - 20.46 Treatment of ketone A with ethynylithium...Ch. 20 - 20.47 Explain why metal hydride reduction gives an...Ch. 20 - Prob. 20.48PCh. 20 - 20.49 Identify the lettered compounds in the...Ch. 20 - Prob. 20.50PCh. 20 - 20.51 Draw a stepwise mechanism for the following...Ch. 20 - 20.52 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.53PCh. 20 - 20.54 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.55PCh. 20 - Prob. 20.56PCh. 20 - 20.57 What ester and Grignard reagent are needed...Ch. 20 - 20.58 What organolithium reagent and carbonyl...Ch. 20 - 20.59 What epoxide and organometallic reagent are...Ch. 20 - Prob. 20.60PCh. 20 - 20.61 Propose two different methods to synthesize...Ch. 20 - 20.62 Synthesize each compound from cyclohexanol...Ch. 20 - 20.63 Convert propan-2-ol into each compound....Ch. 20 - 20.64 Convert benzene into each compound. You may...Ch. 20 - 20.65 Design a synthesis of each compound from...Ch. 20 - 20.66 Synthesize each compound from the given...Ch. 20 - Prob. 20.67PCh. 20 - Prob. 20.68PCh. 20 - 20.69 An unknown compound A (molecular formula )...Ch. 20 - 20.70 Treatment of compound C (molecular formula )...Ch. 20 - 20.71 Treatment of compound E (molecular formula )...Ch. 20 - 20.72 Reaction of butanenitrile () with methyl...Ch. 20 - 20.73 Treatment of isobutene with forms a...Ch. 20 - 20.74 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.75PCh. 20 - 20.76 Lithium tri-sec-butylborohydride, also known...Ch. 20 - Prob. 20.77PCh. 20 - Prob. 20.78PCh. 20 - Prob. 20.79PCh. 20 - 20.80 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.81P
Knowledge Booster
Similar questions
- Indicate how to obtain the compound 2-Hydroxy-2-phenylacetonitrile from phenylmethanol.arrow_forwardIndicate the reagent needed to go from cyclopentane-CH2-CHO to cyclopentane-CH2-CH=CH-C6H5.arrow_forwardesc Write the systematic name of each organic molecule: structure CH3 CH3-C=CH2 CH3-CH2-C-CH2-CH3 CH-CH3 CH3 ☐ ☐ ☐ CI-CH-CH=CH2 Explanation Check F1 F2 name 80 F3 F4 F5 F6 A 7 ! 2 # 3 4 % 5 6 & 7 Q W E R Y FT 2025 Mcarrow_forward
- Two reactants X and Z are required to convert the compound CH3-CH2-CH2Br to the compound CH3-CH2-CH=P(C6H5)3. State reactants X and Z.arrow_forward2. Write a reasonable mechanism that converts the reactants into the products. Avoid issues A-U from the previous page. You can use any number of steps (it does not have to be a one-step mechanism). Do not use any other chemicals (solvents, acids, bases, etc.) in your mechanism. 2 2 H ΗΘarrow_forwardFor the following reaction, the partial pressures were determined for the reaction components as shownbelow. Is the reaction at equilibrium? If not, in which direction will it proceed?I2 (g) + Cl2 (g) ⇋ 2 ICl (g) Kp = 81.9 partial pressures: I2 = 0.114 atm; Cl2 = 0.102 atm; ICl = 0.355 atmarrow_forward
- Ch. 4- Precipitation Reactions Worksheet Write balanced, complete ionic, and net ionic equations for the following reactions that mav produce precipitates. Use NR to indicate no reaction Ave 1\ +3 =6 Fe + V-2 Na S04 13. Write the balanced equation for the reaction of iron (III) phosphate with sodium sulfate to make iron (III) sulfate and sodium phosphate. 2FePO4 + M, Soy a) If you perform this reaction with 25 grams of iron (III) phosphate and an excess of sodium sulfate, how many grams of iron (III) sulfate can you make? 21 Fe 2 3x 1 Na 3 25g Fe Ingle 150,829 Indes 2 nol 3 1335 349.89 35.90 Ihol & Sanz Fez Bak heck 3x1 50ab) If 18.5 grams of iron (III) sulfate are actually made when you do this reaction, what is your Poy percent yield? 118.5 259-1-100 51.4% (0.74)x100610 335 If you do this reaction with 15 grams of sodium sulfate and get a 65.0% yield, how many grams of sodium phosphate will you make? 10.59 14. Ammonia is produced from the reaction of nitrogen and hydrogen according…arrow_forward== Functional Groups Identifying and drawing hemiacetals and acetals In the drawing area below, create an acetal with 1 isopropoxy group, 1 hydroxyl group, and a total of 10 carbon atoms. Explanation Click and drag to start drawing a structure. Check G +arrow_forwardState the products (formulas) of the reaction of acetophenone with iodine and NaOH.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning