Chemistry: The Molecular Nature of Matter
Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 20, Problem 114RQ
Interpretation Introduction

Interpretation:

The kind of decay that produces 234Ac from 234Th is to be identified.

Concept Introduction:

In nuclear reactions, the nucleus of an atom either combines or breaks down to form the nucleus of other atoms. Nuclear emission may occur in the form of alpha emission, beta emission, or positron emission.

Positrons are the antiparticles of electrons that are emitted by synthetic isotopes. They have the same mass as that of an electron, but a positive charge instead of negative.

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.

Chapter 20 Solutions

Chemistry: The Molecular Nature of Matter

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