Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 20, Problem 10PE
Interpretation Introduction
Interpretation:
The most probable form for the radioactive decay of Cm
Concept Introduction:
The
There is a difference between chemical reaction and nuclear reaction. A chemical reaction involves atoms, molecules and electrons whereas a nuclear reaction includes the nucleus of an atom.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 20 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 20 - Prob. 1PECh. 20 - Prob. 2PECh. 20 - Prob. 3PECh. 20 - Prob. 4PECh. 20 - Prob. 5PECh. 20 - Prob. 6PECh. 20 - Prob. 7PECh. 20 - Prob. 8PECh. 20 - Prob. 9PECh. 20 - Prob. 10PE
Ch. 20 - Prob. 11PECh. 20 - Prob. 12PECh. 20 - Prob. 13PECh. 20 - Prob. 14PECh. 20 - Prob. 15PECh. 20 - Prob. 1RQCh. 20 - Conservation of Mass and Energy
20.2 How can we...Ch. 20 - Conservation of Mass and Energy
20.3 State the...Ch. 20 - Conservation of Mass and Energy What is the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQCh. 20 - Prob. 11RQCh. 20 - Prob. 12RQCh. 20 - Prob. 13RQCh. 20 - Prob. 14RQCh. 20 - Prob. 15RQCh. 20 - Prob. 16RQCh. 20 - Prob. 17RQCh. 20 - Prob. 18RQCh. 20 - Prob. 19RQCh. 20 - Band of Stability
20.20 Although lead-164 has two...Ch. 20 - Prob. 21RQCh. 20 - Prob. 22RQCh. 20 - Prob. 23RQCh. 20 - Prob. 24RQCh. 20 - Prob. 25RQCh. 20 - Prob. 26RQCh. 20 - Prob. 27RQCh. 20 - Prob. 28RQCh. 20 - Prob. 29RQCh. 20 - Prob. 30RQCh. 20 - Prob. 31RQCh. 20 - Prob. 32RQCh. 20 - Prob. 33RQCh. 20 - Prob. 34RQCh. 20 - Prob. 35RQCh. 20 - Prob. 37RQCh. 20 - Prob. 38RQCh. 20 - Prob. 39RQCh. 20 - Prob. 40RQCh. 20 - Prob. 41RQCh. 20 - Prob. 42RQCh. 20 - Prob. 43RQCh. 20 - Prob. 44RQCh. 20 - Prob. 45RQCh. 20 - Prob. 46RQCh. 20 - Prob. 47RQCh. 20 - Prob. 48RQCh. 20 - Prob. 49RQCh. 20 - Prob. 50RQCh. 20 - Prob. 51RQCh. 20 - Conservation of Mass and Energy Calculate the...Ch. 20 - Prob. 53RQCh. 20 - Prob. 54RQCh. 20 - Prob. 55RQCh. 20 - Prob. 56RQCh. 20 - Prob. 57RQCh. 20 - Prob. 58RQCh. 20 - Prob. 59RQCh. 20 - Prob. 60RQCh. 20 - Prob. 61RQCh. 20 - Prob. 62RQCh. 20 - Prob. 63RQCh. 20 - Prob. 64RQCh. 20 - Prob. 65RQCh. 20 - Prob. 66RQCh. 20 - Prob. 67RQCh. 20 - Prob. 68RQCh. 20 - Prob. 69RQCh. 20 - Prob. 70RQCh. 20 - Prob. 71RQCh. 20 - Prob. 72RQCh. 20 - Prob. 73RQCh. 20 - Prob. 74RQCh. 20 - Prob. 75RQCh. 20 - Prob. 76RQCh. 20 - Prob. 77RQCh. 20 - Prob. 78RQCh. 20 - Prob. 79RQCh. 20 - Prob. 80RQCh. 20 - Prob. 81RQCh. 20 - Prob. 82RQCh. 20 - Prob. 83RQCh. 20 - Prob. 84RQCh. 20 - Prob. 85RQCh. 20 - Prob. 86RQCh. 20 - Prob. 87RQCh. 20 - Prob. 88RQCh. 20 - Prob. 89RQCh. 20 - Prob. 90RQCh. 20 - Prob. 91RQCh. 20 - Prob. 92RQCh. 20 - Prob. 93RQCh. 20 - Prob. 94RQCh. 20 - Prob. 95RQCh. 20 - Prob. 96RQCh. 20 - Prob. 97RQCh. 20 - Prob. 98RQCh. 20 - Prob. 99RQCh. 20 - Prob. 100RQCh. 20 - Prob. 101RQCh. 20 - Prob. 102RQCh. 20 - Prob. 103RQCh. 20 - Prob. 104RQCh. 20 - Prob. 105RQCh. 20 - Prob. 106RQCh. 20 - Prob. 107RQCh. 20 - Prob. 108RQCh. 20 - Prob. 109RQCh. 20 - Prob. 110RQCh. 20 - Prob. 111RQCh. 20 - Prob. 112RQCh. 20 - Prob. 113RQCh. 20 - Prob. 114RQCh. 20 - Prob. 115RQCh. 20 - Prob. 116RQCh. 20 - Prob. 117RQCh. 20 - Prob. 118RQCh. 20 - Prob. 119RQCh. 20 - Prob. 120RQCh. 20 - Prob. 121RQCh. 20 - Prob. 122RQCh. 20 - Prob. 123RQCh. 20 - Prob. 124RQCh. 20 - Prob. 125RQCh. 20 - A complex ion of chromium(III) with oxalate ion...Ch. 20 - Prob. 127RQCh. 20 - Prob. 128RQCh. 20 - Prob. 129RQCh. 20 - Prob. 132RQ
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Similar questions
- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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