The two naturally occurring isotopes of chlorine are 25 Cl ( 34 .9689 u, 75 .77% ) and 27 Cl ( 36 .9658 u, 24 .23% ) . The two naturally occurring isotopesof bromine are 72 Br ( 78 .9133 u, 50 .69% ) and 81 Br ( 80 .9163 u, 49 .31% ) . Chlorine and bromine combine to form bromine monochloride, BrCl. Sketch a mass spectrum for BrCl with the relative number of molecules plotted against molecular mass (similar to Figure 2.14).
The two naturally occurring isotopes of chlorine are 25 Cl ( 34 .9689 u, 75 .77% ) and 27 Cl ( 36 .9658 u, 24 .23% ) . The two naturally occurring isotopesof bromine are 72 Br ( 78 .9133 u, 50 .69% ) and 81 Br ( 80 .9163 u, 49 .31% ) . Chlorine and bromine combine to form bromine monochloride, BrCl. Sketch a mass spectrum for BrCl with the relative number of molecules plotted against molecular mass (similar to Figure 2.14).
Solution Summary: The author explains the mass spectrum of BrCl which contains relative number of molecules plotted against the molecular mass.
The two naturally occurring isotopes of chlorine are
25
Cl
(
34
.9689 u, 75
.77%
)
and
27
Cl
(
36
.9658 u, 24
.23%
)
. The two naturally occurring isotopesof bromine are
72
Br
(
78
.9133 u, 50
.69%
)
and
81
Br
(
80
.9163 u, 49
.31%
)
. Chlorine and bromine combine to form bromine monochloride, BrCl. Sketch a mass spectrum for BrCl with the relative number of molecules plotted against molecular mass (similar to Figure 2.14).
Reagan is doing an atomic absorption experiment that requires a set of zinc standards in the 0.4-
1.6 ppm range. A 1000 ppm Zn solution was prepared by dissolving the necessary amount of
solid Zn(NO3)2 in water. The standards can be prepared by diluting the 1000 ppm Zn solution.
Table 1 shows one possible set of serial dilutions (stepwise dilution of a solution) that Reagan
could perform to make the necessary standards. Solution A was prepared by diluting 5.00 ml of
the 1000 ppm Zn standard to 50.00 ml. Solutions C-E are called "calibration standards" because
they will be used to calibrate the atomic absorption spectrometer.
Table 1: Dilutions of Zinc Solutions
Solution
Zinc Solution
Volume
Diluted Solution
Concentration
used
volume
(ppm Zn)
(mL)
(mL)
concentration
(ppm Zn)
Solution
concentration
A
1000
5.00
50.00
1.00×10²
(ppm
Zn(NO3)2)
2.90×10²
Solution
concentration
(M Zn(NO3)2
1.53×10-3
B
Solution A 5.00
100.00
5.00
C
Solution B 5.00 50.00
0.50
7.65×10-6
D
Solution B 10.00 50.00…
Chapter 2 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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