
General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Question
Chapter 2, Problem 87IAE
Interpretation Introduction
Interpretation:
The volume of unreacted zinc needs to be calculated.
Concept introduction:
The number of moles can be calculated from mass and molar mass as follows:
Here, m is mass and M is molar mass.
The density of a substance is related to mass and volume as follows:
Here, m is mass and V is volume.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 2 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 2 - When an iron object rusts, its mass increases....Ch. 2 - When a strip of magnesium metal is burned in air...Ch. 2 - A 0.406 g sample of magnesium reacts with oxygen,...Ch. 2 - A 1.446 g sample of potassium reacts with 8.178 g...Ch. 2 - When a solid mixture consisting of 10.500 g...Ch. 2 - Within the limits of experimental error, showthat...Ch. 2 - In Example 2-1, we established flat the mass ratio...Ch. 2 - Samples of pure carbon weighing 3.62, 5.91, and...Ch. 2 - In one experiment sodium was allowed to react with...Ch. 2 - When 3.06 g hydrogen was allowed to react with an...
Ch. 2 - In one experiment, he burning of 0.312 g sulfur...Ch. 2 - In one experiment, the reaction of 1.00 g mercury...Ch. 2 - Sulfur forms two compounds with oxygen. In...Ch. 2 - Phosphorus forms two compounds chlorine.In be...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - There two oxide of copper. One oxide has 20%...Ch. 2 - The two oxides of carbon described on page 38 were...Ch. 2 - The following observations were made for a series...Ch. 2 - In an experiment similar to that described in...Ch. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - The following radioactive isotopes have...Ch. 2 - For the isotope H202g , express the percentage of...Ch. 2 - Complete the following table. What minimum amount...Ch. 2 - Arrange the following species order of increasing...Ch. 2 - For the atom 108Pd with mass 107.90389 u,...Ch. 2 - For the ion R225a24 with a mass of 228.030 u,...Ch. 2 - An isotope of silver has a mass that is 6.68374...Ch. 2 - Prob. 30ECh. 2 - The following data on isotopic masses are from a...Ch. 2 - The following ratios of masses were obtained with...Ch. 2 - Which of the following species has a. equal...Ch. 2 - Prob. 34ECh. 2 - An isotope with mass numbers 44 has four more...Ch. 2 - Identify the isotope X that has one more neutron...Ch. 2 - Iodine has many radioactive isotopes.Iodine-123 is...Ch. 2 - Iodine-131 is a radioactive isotope that has...Ch. 2 - Americium-241 is aradioactive isotope that is used...Ch. 2 - Some foods are made safer to eat by being exposed...Ch. 2 - Which statement is probably true concerning the...Ch. 2 - The mass of e carbon-12 atom is taken to be...Ch. 2 - Magnesium has three naturally occurring isotopes....Ch. 2 - There are four naturally occurring isotopes of...Ch. 2 - The two naturally occurring isotopes of silver...Ch. 2 - Gallium has two naturally occurring isotopes. One...Ch. 2 - The three naturally occurring isotopes of...Ch. 2 - Use the conventional atomic mass of boron to...Ch. 2 - A mass spectrum of germanium displayed peaks at...Ch. 2 - Prob. 50ECh. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Determine a. the number of moles of Zn in a 415.0...Ch. 2 - Determine a. the number of Kr atoms in a 5.25 mg...Ch. 2 - How many Cu atoms are present in a piece of...Ch. 2 - How many atoms are present in a 50.0 cm2 sample of...Ch. 2 - How many 204Pb atoms are present in a piece of...Ch. 2 - A particular lead-cadmium alloy is 8.0% cadmium by...Ch. 2 - Prob. 63ECh. 2 - During a severe episode of air pollution, the...Ch. 2 - Without doing detailed calculations, determine...Ch. 2 - Prob. 66ECh. 2 - A solution was prepared by dissolving 2.50 g...Ch. 2 - Prob. 68IAECh. 2 - Fluorine has a single atomic species, 19F ....Ch. 2 - Prob. 70IAECh. 2 - Use the fundamental definitions and statements...Ch. 2 - In each case, identify the element in question. a....Ch. 2 - Determine the only possible +2 ion for which the...Ch. 2 - Prob. 74IAECh. 2 - Suppose we redefined the atomic mass scale by...Ch. 2 - The two naturally occurring isotopes of nitrogen...Ch. 2 - Prob. 77IAECh. 2 - Germanium has three major naturally occurring...Ch. 2 - From densities of the lines in the mass spectrum...Ch. 2 - The two naturally occurring isotopes of chlorine...Ch. 2 - How many atoms are present in a 1.50 m length of...Ch. 2 - Monel metal is a corrosion-resistant copper-nickel...Ch. 2 - Deuterium, 2H(2.0140u) , is sometimes used to...Ch. 2 - An alloy that melts at about the boiling pointof...Ch. 2 - A particular silver solder (used in the...Ch. 2 - Prob. 86IAECh. 2 - Prob. 87IAECh. 2 - Atoms are spherical and so when silver atoms pack...Ch. 2 - The data Lavoisier obtained in the experiment...Ch. 2 - Prob. 90FPCh. 2 - Prob. 91FPCh. 2 - German chemist Fritz Haber proposed paying off the...Ch. 2 - Mass spectrometry is one of the most versatile and...Ch. 2 - In your own words, define or explain these terms...Ch. 2 - Briefly describe a. the law of conservation of...Ch. 2 - Explain the important distinctions between each...Ch. 2 - A certain element contains one atom of mass 10.013...Ch. 2 - When 10.0 g zinc and 8.0 g sulfur are allowed to...Ch. 2 - Prob. 99SAECh. 2 - An attempt was made to determine he atomic mass of...Ch. 2 - Cathode rays a. may be positively or negatively...Ch. 2 - The scattering of a particles by thin metal foils...Ch. 2 - Prob. 103SAECh. 2 - Which of the following is not a fundamental...Ch. 2 - Which of the following scientists did not...Ch. 2 - Prob. 106SAECh. 2 - Prob. 107SAECh. 2 - Prob. 108SAECh. 2 - Prob. 109SAECh. 2 - The two species that have the same number of...Ch. 2 - Prob. 111SAECh. 2 - Prob. 112SAECh. 2 - A 5.585-kg sample of iron (Fe) contains a.10.0...Ch. 2 - A 91.84 g sample of Ti contains (a) 4.175 mol of...Ch. 2 - There are three common iron-oxygen compounds. The...Ch. 2 - The four naturally occurring isotopes of strontium...Ch. 2 - Prob. 117SAECh. 2 - Prob. 118SAE
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