
General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Question
Chapter 2, Problem 50E
Interpretation Introduction
Interpretation:
The number of different HCl molecules possible from the combination of 35Cl, 37Cl, 2H and 3H atoms need to be deduced
Concept introduction:
- Atoms are composed of fundamental subatomic particles: protons, neutrons and electrons and are characterized by
atomic mass andatomic number . - Isotopes are atoms of the same element which have the same atomic number but different atomic masses.
Atomic mass = number of protons + number of neutrons.
Atomic number = number of protons = number of electrons.
Interpretation Introduction
Interpretation:
The first and second most
Concept introduction:
- Isotopes are atoms of the same element which have the same atomic number but different atomic masses.
- Isotopic abundance refers to the amount of a particular isotope present in a given element or a compound.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
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constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
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(4 points)
Chapter 2 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 2 - When an iron object rusts, its mass increases....Ch. 2 - When a strip of magnesium metal is burned in air...Ch. 2 - A 0.406 g sample of magnesium reacts with oxygen,...Ch. 2 - A 1.446 g sample of potassium reacts with 8.178 g...Ch. 2 - When a solid mixture consisting of 10.500 g...Ch. 2 - Within the limits of experimental error, showthat...Ch. 2 - In Example 2-1, we established flat the mass ratio...Ch. 2 - Samples of pure carbon weighing 3.62, 5.91, and...Ch. 2 - In one experiment sodium was allowed to react with...Ch. 2 - When 3.06 g hydrogen was allowed to react with an...
Ch. 2 - In one experiment, he burning of 0.312 g sulfur...Ch. 2 - In one experiment, the reaction of 1.00 g mercury...Ch. 2 - Sulfur forms two compounds with oxygen. In...Ch. 2 - Phosphorus forms two compounds chlorine.In be...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - There two oxide of copper. One oxide has 20%...Ch. 2 - The two oxides of carbon described on page 38 were...Ch. 2 - The following observations were made for a series...Ch. 2 - In an experiment similar to that described in...Ch. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - The following radioactive isotopes have...Ch. 2 - For the isotope H202g , express the percentage of...Ch. 2 - Complete the following table. What minimum amount...Ch. 2 - Arrange the following species order of increasing...Ch. 2 - For the atom 108Pd with mass 107.90389 u,...Ch. 2 - For the ion R225a24 with a mass of 228.030 u,...Ch. 2 - An isotope of silver has a mass that is 6.68374...Ch. 2 - Prob. 30ECh. 2 - The following data on isotopic masses are from a...Ch. 2 - The following ratios of masses were obtained with...Ch. 2 - Which of the following species has a. equal...Ch. 2 - Prob. 34ECh. 2 - An isotope with mass numbers 44 has four more...Ch. 2 - Identify the isotope X that has one more neutron...Ch. 2 - Iodine has many radioactive isotopes.Iodine-123 is...Ch. 2 - Iodine-131 is a radioactive isotope that has...Ch. 2 - Americium-241 is aradioactive isotope that is used...Ch. 2 - Some foods are made safer to eat by being exposed...Ch. 2 - Which statement is probably true concerning the...Ch. 2 - The mass of e carbon-12 atom is taken to be...Ch. 2 - Magnesium has three naturally occurring isotopes....Ch. 2 - There are four naturally occurring isotopes of...Ch. 2 - The two naturally occurring isotopes of silver...Ch. 2 - Gallium has two naturally occurring isotopes. One...Ch. 2 - The three naturally occurring isotopes of...Ch. 2 - Use the conventional atomic mass of boron to...Ch. 2 - A mass spectrum of germanium displayed peaks at...Ch. 2 - Prob. 50ECh. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Determine a. the number of moles of Zn in a 415.0...Ch. 2 - Determine a. the number of Kr atoms in a 5.25 mg...Ch. 2 - How many Cu atoms are present in a piece of...Ch. 2 - How many atoms are present in a 50.0 cm2 sample of...Ch. 2 - How many 204Pb atoms are present in a piece of...Ch. 2 - A particular lead-cadmium alloy is 8.0% cadmium by...Ch. 2 - Prob. 63ECh. 2 - During a severe episode of air pollution, the...Ch. 2 - Without doing detailed calculations, determine...Ch. 2 - Prob. 66ECh. 2 - A solution was prepared by dissolving 2.50 g...Ch. 2 - Prob. 68IAECh. 2 - Fluorine has a single atomic species, 19F ....Ch. 2 - Prob. 70IAECh. 2 - Use the fundamental definitions and statements...Ch. 2 - In each case, identify the element in question. a....Ch. 2 - Determine the only possible +2 ion for which the...Ch. 2 - Prob. 74IAECh. 2 - Suppose we redefined the atomic mass scale by...Ch. 2 - The two naturally occurring isotopes of nitrogen...Ch. 2 - Prob. 77IAECh. 2 - Germanium has three major naturally occurring...Ch. 2 - From densities of the lines in the mass spectrum...Ch. 2 - The two naturally occurring isotopes of chlorine...Ch. 2 - How many atoms are present in a 1.50 m length of...Ch. 2 - Monel metal is a corrosion-resistant copper-nickel...Ch. 2 - Deuterium, 2H(2.0140u) , is sometimes used to...Ch. 2 - An alloy that melts at about the boiling pointof...Ch. 2 - A particular silver solder (used in the...Ch. 2 - Prob. 86IAECh. 2 - Prob. 87IAECh. 2 - Atoms are spherical and so when silver atoms pack...Ch. 2 - The data Lavoisier obtained in the experiment...Ch. 2 - Prob. 90FPCh. 2 - Prob. 91FPCh. 2 - German chemist Fritz Haber proposed paying off the...Ch. 2 - Mass spectrometry is one of the most versatile and...Ch. 2 - In your own words, define or explain these terms...Ch. 2 - Briefly describe a. the law of conservation of...Ch. 2 - Explain the important distinctions between each...Ch. 2 - A certain element contains one atom of mass 10.013...Ch. 2 - When 10.0 g zinc and 8.0 g sulfur are allowed to...Ch. 2 - Prob. 99SAECh. 2 - An attempt was made to determine he atomic mass of...Ch. 2 - Cathode rays a. may be positively or negatively...Ch. 2 - The scattering of a particles by thin metal foils...Ch. 2 - Prob. 103SAECh. 2 - Which of the following is not a fundamental...Ch. 2 - Which of the following scientists did not...Ch. 2 - Prob. 106SAECh. 2 - Prob. 107SAECh. 2 - Prob. 108SAECh. 2 - Prob. 109SAECh. 2 - The two species that have the same number of...Ch. 2 - Prob. 111SAECh. 2 - Prob. 112SAECh. 2 - A 5.585-kg sample of iron (Fe) contains a.10.0...Ch. 2 - A 91.84 g sample of Ti contains (a) 4.175 mol of...Ch. 2 - There are three common iron-oxygen compounds. 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