General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 2, Problem 58E
Determine
a. the number of Kr atoms in a 5.25 mg sample of krypton
b. the molar mass, M, and identity of an element if the mass of a
c. the mass of a sample of phosphorus that contains the same number of atoms as 44.75 g of magnesium
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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO
dimethylsulfoxide).
The emission data in cps displayed in Table 1 is reported to two decimal places by the
chemist. However, the instrument output is shown in Table 2.
Table 2. Iron emission from ICP-AES
Sample
Blank
Standard
Emission, cps
579.503252562
9308340.13122
Unknown Sample
343.232365741
Did the chemist make the correct choice in how they choose to display the data up in Table
1? Choose the best explanation from the choices below.
No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated.
Doing so would eliminate significant information.
No. Since the instrument calculates 5 decimal places for the standard, all of the values should be
limited to the same number. The other decimal places are not significant for the blank and unknown
sample.
Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware
can report values to 2 decimal places, and this establishes our number of significant figures.
Yes. Instrumental data…
Chapter 2 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 2 - When an iron object rusts, its mass increases....Ch. 2 - When a strip of magnesium metal is burned in air...Ch. 2 - A 0.406 g sample of magnesium reacts with oxygen,...Ch. 2 - A 1.446 g sample of potassium reacts with 8.178 g...Ch. 2 - When a solid mixture consisting of 10.500 g...Ch. 2 - Within the limits of experimental error, showthat...Ch. 2 - In Example 2-1, we established flat the mass ratio...Ch. 2 - Samples of pure carbon weighing 3.62, 5.91, and...Ch. 2 - In one experiment sodium was allowed to react with...Ch. 2 - When 3.06 g hydrogen was allowed to react with an...
Ch. 2 - In one experiment, he burning of 0.312 g sulfur...Ch. 2 - In one experiment, the reaction of 1.00 g mercury...Ch. 2 - Sulfur forms two compounds with oxygen. In...Ch. 2 - Phosphorus forms two compounds chlorine.In be...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - The following data were obtained for compounds of...Ch. 2 - There two oxide of copper. One oxide has 20%...Ch. 2 - The two oxides of carbon described on page 38 were...Ch. 2 - The following observations were made for a series...Ch. 2 - In an experiment similar to that described in...Ch. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - The following radioactive isotopes have...Ch. 2 - For the isotope H202g , express the percentage of...Ch. 2 - Complete the following table. What minimum amount...Ch. 2 - Arrange the following species order of increasing...Ch. 2 - For the atom 108Pd with mass 107.90389 u,...Ch. 2 - For the ion R225a24 with a mass of 228.030 u,...Ch. 2 - An isotope of silver has a mass that is 6.68374...Ch. 2 - Prob. 30ECh. 2 - The following data on isotopic masses are from a...Ch. 2 - The following ratios of masses were obtained with...Ch. 2 - Which of the following species has a. equal...Ch. 2 - Prob. 34ECh. 2 - An isotope with mass numbers 44 has four more...Ch. 2 - Identify the isotope X that has one more neutron...Ch. 2 - Iodine has many radioactive isotopes.Iodine-123 is...Ch. 2 - Iodine-131 is a radioactive isotope that has...Ch. 2 - Americium-241 is aradioactive isotope that is used...Ch. 2 - Some foods are made safer to eat by being exposed...Ch. 2 - Which statement is probably true concerning the...Ch. 2 - The mass of e carbon-12 atom is taken to be...Ch. 2 - Magnesium has three naturally occurring isotopes....Ch. 2 - There are four naturally occurring isotopes of...Ch. 2 - The two naturally occurring isotopes of silver...Ch. 2 - Gallium has two naturally occurring isotopes. One...Ch. 2 - The three naturally occurring isotopes of...Ch. 2 - Use the conventional atomic mass of boron to...Ch. 2 - A mass spectrum of germanium displayed peaks at...Ch. 2 - Prob. 50ECh. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Refer to the periodic table inside the front cover...Ch. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Determine a. the number of moles of Zn in a 415.0...Ch. 2 - Determine a. the number of Kr atoms in a 5.25 mg...Ch. 2 - How many Cu atoms are present in a piece of...Ch. 2 - How many atoms are present in a 50.0 cm2 sample of...Ch. 2 - How many 204Pb atoms are present in a piece of...Ch. 2 - A particular lead-cadmium alloy is 8.0% cadmium by...Ch. 2 - Prob. 63ECh. 2 - During a severe episode of air pollution, the...Ch. 2 - Without doing detailed calculations, determine...Ch. 2 - Prob. 66ECh. 2 - A solution was prepared by dissolving 2.50 g...Ch. 2 - Prob. 68IAECh. 2 - Fluorine has a single atomic species, 19F ....Ch. 2 - Prob. 70IAECh. 2 - Use the fundamental definitions and statements...Ch. 2 - In each case, identify the element in question. a....Ch. 2 - Determine the only possible +2 ion for which the...Ch. 2 - Prob. 74IAECh. 2 - Suppose we redefined the atomic mass scale by...Ch. 2 - The two naturally occurring isotopes of nitrogen...Ch. 2 - Prob. 77IAECh. 2 - Germanium has three major naturally occurring...Ch. 2 - From densities of the lines in the mass spectrum...Ch. 2 - The two naturally occurring isotopes of chlorine...Ch. 2 - How many atoms are present in a 1.50 m length of...Ch. 2 - Monel metal is a corrosion-resistant copper-nickel...Ch. 2 - Deuterium, 2H(2.0140u) , is sometimes used to...Ch. 2 - An alloy that melts at about the boiling pointof...Ch. 2 - A particular silver solder (used in the...Ch. 2 - Prob. 86IAECh. 2 - Prob. 87IAECh. 2 - Atoms are spherical and so when silver atoms pack...Ch. 2 - The data Lavoisier obtained in the experiment...Ch. 2 - Prob. 90FPCh. 2 - Prob. 91FPCh. 2 - German chemist Fritz Haber proposed paying off the...Ch. 2 - Mass spectrometry is one of the most versatile and...Ch. 2 - In your own words, define or explain these terms...Ch. 2 - Briefly describe a. the law of conservation of...Ch. 2 - Explain the important distinctions between each...Ch. 2 - A certain element contains one atom of mass 10.013...Ch. 2 - When 10.0 g zinc and 8.0 g sulfur are allowed to...Ch. 2 - Prob. 99SAECh. 2 - An attempt was made to determine he atomic mass of...Ch. 2 - Cathode rays a. may be positively or negatively...Ch. 2 - The scattering of a particles by thin metal foils...Ch. 2 - Prob. 103SAECh. 2 - Which of the following is not a fundamental...Ch. 2 - Which of the following scientists did not...Ch. 2 - Prob. 106SAECh. 2 - Prob. 107SAECh. 2 - Prob. 108SAECh. 2 - Prob. 109SAECh. 2 - The two species that have the same number of...Ch. 2 - Prob. 111SAECh. 2 - Prob. 112SAECh. 2 - A 5.585-kg sample of iron (Fe) contains a.10.0...Ch. 2 - A 91.84 g sample of Ti contains (a) 4.175 mol of...Ch. 2 - There are three common iron-oxygen compounds. The...Ch. 2 - The four naturally occurring isotopes of strontium...Ch. 2 - Prob. 117SAECh. 2 - Prob. 118SAE
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