EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 2, Problem 7RQ
Interpretation Introduction
Interpretation:
The possibility to contain more number of significant figures for the calculated answer from a multiplication or division than the measurement used in the calculation has to be given.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 2 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 2.1 - Prob. 2.1PCh. 2.2 - Prob. 2.2PCh. 2.3 - Prob. 2.3PCh. 2.3 - Prob. 2.4PCh. 2.4 - Prob. 2.5PCh. 2.4 - Prob. 2.6PCh. 2.5 - Prob. 2.7PCh. 2.5 - Prob. 2.8PCh. 2.5 - Prob. 2.9PCh. 2.6 - Prob. 2.10P
Ch. 2.6 - Prob. 2.11PCh. 2.6 - Prob. 2.12PCh. 2.6 - Prob. 2.13PCh. 2.6 - Prob. 2.14PCh. 2.6 - Prob. 2.15PCh. 2.7 - Prob. 2.16PCh. 2.7 - Prob. 2.17PCh. 2.7 - Prob. 2.18PCh. 2.7 - Prob. 2.19PCh. 2.8 - Prob. 2.20PCh. 2.8 - Prob. 2.21PCh. 2.9 - Prob. 2.22PCh. 2.9 - Prob. 2.23PCh. 2 - Prob. 1RQCh. 2 - Prob. 2RQCh. 2 - Prob. 3RQCh. 2 - Prob. 4RQCh. 2 - Prob. 5RQCh. 2 - Prob. 6RQCh. 2 - Prob. 7RQCh. 2 - Prob. 8RQCh. 2 - Prob. 9RQCh. 2 - Prob. 10RQCh. 2 - Prob. 11RQCh. 2 - Prob. 12RQCh. 2 - Prob. 13RQCh. 2 - Prob. 14RQCh. 2 - Prob. 15RQCh. 2 - Prob. 16RQCh. 2 - Prob. 17RQCh. 2 - Prob. 18RQCh. 2 - Prob. 19RQCh. 2 - Prob. 20RQCh. 2 - Prob. 21RQCh. 2 - Prob. 1PECh. 2 - Prob. 2PECh. 2 - Prob. 3PECh. 2 - Prob. 4PECh. 2 - Prob. 5PECh. 2 - Prob. 6PECh. 2 - Prob. 7PECh. 2 - Prob. 8PECh. 2 - Prob. 9PECh. 2 - Prob. 10PECh. 2 - Prob. 11PECh. 2 - Prob. 12PECh. 2 - Prob. 13PECh. 2 - Prob. 14PECh. 2 - Prob. 15PECh. 2 - Prob. 16PECh. 2 - Prob. 17PECh. 2 - Prob. 18PECh. 2 - Prob. 19PECh. 2 - Prob. 20PECh. 2 - Prob. 21PECh. 2 - Prob. 22PECh. 2 - Prob. 23PECh. 2 - Prob. 24PECh. 2 - Prob. 25PECh. 2 - Prob. 26PECh. 2 - Prob. 27PECh. 2 - Prob. 28PECh. 2 - Prob. 29PECh. 2 - Prob. 30PECh. 2 - Prob. 31PECh. 2 - Prob. 32PECh. 2 - Prob. 33PECh. 2 - Prob. 34PECh. 2 - Prob. 35PECh. 2 - Prob. 36PECh. 2 - Prob. 37PECh. 2 - Prob. 38PECh. 2 - Prob. 39PECh. 2 - Prob. 40PECh. 2 - Prob. 41PECh. 2 - Prob. 42PECh. 2 - Prob. 43PECh. 2 - Prob. 44PECh. 2 - Prob. 45PECh. 2 - Prob. 46PECh. 2 - Prob. 47PECh. 2 - Prob. 48PECh. 2 - Prob. 49PECh. 2 - Prob. 50PECh. 2 - Prob. 51PECh. 2 - Prob. 52PECh. 2 - Prob. 53PECh. 2 - Prob. 54PECh. 2 - Prob. 55PECh. 2 - Prob. 56PECh. 2 - Prob. 57PECh. 2 - Prob. 58PECh. 2 - Prob. 59PECh. 2 - Prob. 60PECh. 2 - Prob. 61PECh. 2 - Prob. 62PECh. 2 - Prob. 63PECh. 2 - Prob. 64PECh. 2 - Prob. 65PECh. 2 - Prob. 66PECh. 2 - Prob. 67PECh. 2 - Prob. 68PECh. 2 - Prob. 69PECh. 2 - Prob. 70PECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Prob. 80AECh. 2 - Prob. 81AECh. 2 - Prob. 82AECh. 2 - Prob. 83AECh. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Prob. 86AECh. 2 - Prob. 87AECh. 2 - Prob. 88AECh. 2 - Prob. 89AECh. 2 - Prob. 90AECh. 2 - Prob. 91AECh. 2 - Prob. 92AECh. 2 - Prob. 93AECh. 2 - Prob. 94AECh. 2 - Prob. 95AECh. 2 - Prob. 96AECh. 2 - Prob. 97AECh. 2 - Prob. 98AECh. 2 - Prob. 99AECh. 2 - Prob. 100AECh. 2 - Prob. 101AECh. 2 - Prob. 102AECh. 2 - Prob. 103AECh. 2 - Prob. 104AECh. 2 - Prob. 105AECh. 2 - Prob. 106CECh. 2 - Prob. 108CECh. 2 - Prob. 109CECh. 2 - Prob. 110CECh. 2 - Prob. 111CECh. 2 - Prob. 112CE
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