EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Question
Chapter 2, Problem 69PE
(a)
Interpretation Introduction
Interpretation:
The dimensional analysis factors have to be determined.
(b)
Interpretation Introduction
Interpretation:
The number of quarters has to be given.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 2 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 2.1 - Prob. 2.1PCh. 2.2 - Prob. 2.2PCh. 2.3 - Prob. 2.3PCh. 2.3 - Prob. 2.4PCh. 2.4 - Prob. 2.5PCh. 2.4 - Prob. 2.6PCh. 2.5 - Prob. 2.7PCh. 2.5 - Prob. 2.8PCh. 2.5 - Prob. 2.9PCh. 2.6 - Prob. 2.10P
Ch. 2.6 - Prob. 2.11PCh. 2.6 - Prob. 2.12PCh. 2.6 - Prob. 2.13PCh. 2.6 - Prob. 2.14PCh. 2.6 - Prob. 2.15PCh. 2.7 - Prob. 2.16PCh. 2.7 - Prob. 2.17PCh. 2.7 - Prob. 2.18PCh. 2.7 - Prob. 2.19PCh. 2.8 - Prob. 2.20PCh. 2.8 - Prob. 2.21PCh. 2.9 - Prob. 2.22PCh. 2.9 - Prob. 2.23PCh. 2 - Prob. 1RQCh. 2 - Prob. 2RQCh. 2 - Prob. 3RQCh. 2 - Prob. 4RQCh. 2 - Prob. 5RQCh. 2 - Prob. 6RQCh. 2 - Prob. 7RQCh. 2 - Prob. 8RQCh. 2 - Prob. 9RQCh. 2 - Prob. 10RQCh. 2 - Prob. 11RQCh. 2 - Prob. 12RQCh. 2 - Prob. 13RQCh. 2 - Prob. 14RQCh. 2 - Prob. 15RQCh. 2 - Prob. 16RQCh. 2 - Prob. 17RQCh. 2 - Prob. 18RQCh. 2 - Prob. 19RQCh. 2 - Prob. 20RQCh. 2 - Prob. 21RQCh. 2 - Prob. 1PECh. 2 - Prob. 2PECh. 2 - Prob. 3PECh. 2 - Prob. 4PECh. 2 - Prob. 5PECh. 2 - Prob. 6PECh. 2 - Prob. 7PECh. 2 - Prob. 8PECh. 2 - Prob. 9PECh. 2 - Prob. 10PECh. 2 - Prob. 11PECh. 2 - Prob. 12PECh. 2 - Prob. 13PECh. 2 - Prob. 14PECh. 2 - Prob. 15PECh. 2 - Prob. 16PECh. 2 - Prob. 17PECh. 2 - Prob. 18PECh. 2 - Prob. 19PECh. 2 - Prob. 20PECh. 2 - Prob. 21PECh. 2 - Prob. 22PECh. 2 - Prob. 23PECh. 2 - Prob. 24PECh. 2 - Prob. 25PECh. 2 - Prob. 26PECh. 2 - Prob. 27PECh. 2 - Prob. 28PECh. 2 - Prob. 29PECh. 2 - Prob. 30PECh. 2 - Prob. 31PECh. 2 - Prob. 32PECh. 2 - Prob. 33PECh. 2 - Prob. 34PECh. 2 - Prob. 35PECh. 2 - Prob. 36PECh. 2 - Prob. 37PECh. 2 - Prob. 38PECh. 2 - Prob. 39PECh. 2 - Prob. 40PECh. 2 - Prob. 41PECh. 2 - Prob. 42PECh. 2 - Prob. 43PECh. 2 - Prob. 44PECh. 2 - Prob. 45PECh. 2 - Prob. 46PECh. 2 - Prob. 47PECh. 2 - Prob. 48PECh. 2 - Prob. 49PECh. 2 - Prob. 50PECh. 2 - Prob. 51PECh. 2 - Prob. 52PECh. 2 - Prob. 53PECh. 2 - Prob. 54PECh. 2 - Prob. 55PECh. 2 - Prob. 56PECh. 2 - Prob. 57PECh. 2 - Prob. 58PECh. 2 - Prob. 59PECh. 2 - Prob. 60PECh. 2 - Prob. 61PECh. 2 - Prob. 62PECh. 2 - Prob. 63PECh. 2 - Prob. 64PECh. 2 - Prob. 65PECh. 2 - Prob. 66PECh. 2 - Prob. 67PECh. 2 - Prob. 68PECh. 2 - Prob. 69PECh. 2 - Prob. 70PECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Prob. 80AECh. 2 - Prob. 81AECh. 2 - Prob. 82AECh. 2 - Prob. 83AECh. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Prob. 86AECh. 2 - Prob. 87AECh. 2 - Prob. 88AECh. 2 - Prob. 89AECh. 2 - Prob. 90AECh. 2 - Prob. 91AECh. 2 - Prob. 92AECh. 2 - Prob. 93AECh. 2 - Prob. 94AECh. 2 - Prob. 95AECh. 2 - Prob. 96AECh. 2 - Prob. 97AECh. 2 - Prob. 98AECh. 2 - Prob. 99AECh. 2 - Prob. 100AECh. 2 - Prob. 101AECh. 2 - Prob. 102AECh. 2 - Prob. 103AECh. 2 - Prob. 104AECh. 2 - Prob. 105AECh. 2 - Prob. 106CECh. 2 - Prob. 108CECh. 2 - Prob. 109CECh. 2 - Prob. 110CECh. 2 - Prob. 111CECh. 2 - Prob. 112CE
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