Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 2, Problem 76E
Boron has only two naturally occurring isotopes. The mass of boron-10 is 10.01294 amu and the mass of boron-11 is 11.00931 amu. Use the
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 2 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 2 - Prob. 2.1PCh. 2 - For Practice 2.2
Hydrogen and oxygen form both...Ch. 2 - Prob. 2.3PCh. 2 - Prob. 2.4PCh. 2 - Prob. 2.5PCh. 2 - Prob. 2.5MPCh. 2 - Prob. 2.6PCh. 2 - For Practice 2.7 Calculate the amount of copper...Ch. 2 - Prob. 2.7MPCh. 2 - Prob. 2.8P
Ch. 2 - Prob. 2.8MPCh. 2 - For Practice 2.9
A titanium cube contains atoms....Ch. 2 - For More Practice 2.9
Find the number of atoms in...Ch. 2 - Prob. 1SAQCh. 2 - Prob. 2SAQCh. 2 - Q3. Which idea came out of Rutherford’s gold foil...Ch. 2 - A student re-creates the Millikan oil drop...Ch. 2 - Determine the number of protons and neutrons in...Ch. 2 - Prob. 6SAQCh. 2 - Prob. 7SAQCh. 2 - Prob. 8SAQCh. 2 - Prob. 9SAQCh. 2 - Prob. 10SAQCh. 2 - Prob. 11SAQCh. 2 - Prob. 12SAQCh. 2 - Determine the number of atoms in 1.85 mL of...Ch. 2 - A 20.0 g sample of an element contains 4.951023...Ch. 2 - 1. A hydrogen-filled balloon is ignited, and 1.50...Ch. 2 - 2. An automobile gasoline tank holds 21 kg of...Ch. 2 - 3. Two samples of carbon tetrachloride are...Ch. 2 - Prob. 4ECh. 2 - The mass ratio of sodium to fluorine in sodium...Ch. 2 - 6. Upon decomposition, one sample of magnesium...Ch. 2 - 7. Two different compounds containing and oxygen...Ch. 2 - 8. Palladium forms three different compounds with...Ch. 2 - Sulfur and oxygen form both sulfur dioxide and...Ch. 2 - 10. Sulfur and fluorine form several different...Ch. 2 - 11. Which statements are consistent with Dalton’s...Ch. 2 - Which statements are inconsistent with Dalton’s...Ch. 2 - 13. Which statements are consistent with...Ch. 2 - 14. Which statements are inconsistent with...Ch. 2 - A chemist in an imaginary universe, where...Ch. 2 - 16. Imagine a unit of charge called the zorg. A...Ch. 2 - Prob. 17ECh. 2 - 18. How many electrons does it take to equal the...Ch. 2 - Which statements about subatomic particles are...Ch. 2 - 20. Which statements about subatomic particles are...Ch. 2 - Write isotopic symbols of the form AZX for each...Ch. 2 - 22. Write isotopic symbols of the form X-A (e.g.,...Ch. 2 - 23. Determine the number of protons and the number...Ch. 2 - Determine the number of protons and the number of...Ch. 2 - 25. The amount of carbon-14 in artifacts and...Ch. 2 - Urarium-235 is used in nuclear fission. Determine...Ch. 2 - 27. Determine the number of protons and the number...Ch. 2 - Prob. 28ECh. 2 - Prob. 29ECh. 2 - Prob. 30ECh. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - Prob. 33ECh. 2 - Prob. 34ECh. 2 - Prob. 35ECh. 2 - Determine whether or not each element is a...Ch. 2 - Prob. 37ECh. 2 - Prob. 38ECh. 2 - Prob. 39ECh. 2 - Prob. 40ECh. 2 - Prob. 41ECh. 2 - Prob. 42ECh. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Prob. 47ECh. 2 - Prob. 48ECh. 2 - Prob. 49ECh. 2 - What is the mass of 9.711022 platinum atoms?Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - A 7.3 g sample of HCN contains 0.290 g of H and...Ch. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - An a particle, 4He2+, has a mass of 4.00151 amu....Ch. 2 - Prob. 62ECh. 2 - Nuclei with the same number of neutrons but...Ch. 2 - Prob. 64ECh. 2 - Prob. 65ECh. 2 - Prob. 66ECh. 2 - Prob. 67ECh. 2 - Prob. 68ECh. 2 - Prob. 69ECh. 2 - Prob. 70ECh. 2 - Prob. 71ECh. 2 - Prob. 72ECh. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - Boron has only two naturally occurring isotopes....Ch. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - The U.S. Environmental Protection Agency (EPA)...Ch. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Prob. 84ECh. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - 87. The ratio of the mass of O to the mass of N in...Ch. 2 - Prob. 88ECh. 2 - Prob. 89ECh. 2 - Suppose that one of Millikan’s oil drops had a...Ch. 2 - Prob. 91ECh. 2 - 92. As we say in the previous problem, lithium has...Ch. 2 - Prob. 93ECh. 2 - Prob. 94ECh. 2 - The atomic radii of the isotopes of an element are...
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