Chapter 2, Problem 51DSP

Interpretation Introduction

Interpretation:

The alkane which is expected to give two constitutionally isomeric alcohols on oxidation is to be determined.

Concept introduction:

The fungus Pseudomonas oleovorans oxidizes the ${\text{CH}}_{\text{3}}$ groups at the end of the carbon chain faster than the ${\text{CH}}_{\text{3}}$ branch and faster than the ${\text{CH}}_2$ and $\text{CH}$ units within the chain and convert the alkane to a corresponding alcohol.

Oxidation of these terminal methyl groups converts them to the corresponding ${\text{-CH}}_{\text{2}}\text{OH}$ groups.