Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.90PAE
2.94 Use a molecular level description to distinguish between LDPE and HDPE.
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 2 Solutions
Chemistry for Engineering Students
Ch. 2 - Name at least three common polymers and give...Ch. 2 - Prob. 2COCh. 2 - Describe the nuclear model for the atom and...Ch. 2 - Prob. 4COCh. 2 - Prob. 5COCh. 2 - Prob. 6COCh. 2 - Prob. 7COCh. 2 - Prob. 8COCh. 2 - Prob. 9COCh. 2 - Prob. 10CO
Ch. 2 - Prob. 2.1PAECh. 2 - How do polymers compare to their respective...Ch. 2 - Look around you and identify several objects that...Ch. 2 - Prob. 2.4PAECh. 2 - The fact that a polymer’s physical properties...Ch. 2 - Use the web to research the amount of PVC polymer...Ch. 2 - Prob. 2.7PAECh. 2 - Prob. 2.8PAECh. 2 - Why is the number of protons called the atomic...Ch. 2 - 2.10 Which isotope in each pair contains more...Ch. 2 - 2.11 Define the term isotope.Ch. 2 - 2.12 Write the complete atomic symbol for each of...Ch. 2 - 2.13 How many electrons, protons, and neutrons are...Ch. 2 - 2.14 Consider the following nuclear symbols. How...Ch. 2 - 2.15 Mercury is 16.716 times more massive than...Ch. 2 - Prob. 2.16PAECh. 2 - Prob. 2.17PAECh. 2 - The element gallium, used in gallium arsenide...Ch. 2 - 2.17 The atomic weight of copper is 63.55 amu....Ch. 2 - The following table presents the abundances and...Ch. 2 - 2.19 Naturally occurring uranium consists of two...Ch. 2 - Prob. 2.22PAECh. 2 - Prob. 2.23PAECh. 2 - Prob. 2.24PAECh. 2 - Prob. 2.25PAECh. 2 - 2.22 Provide the symbol of the following...Ch. 2 - Prob. 2.27PAECh. 2 - 2.24 Identify each of the following species as an...Ch. 2 - 2.25 Write the atomic symbol for the element whose...Ch. 2 - 2.26 In what region of the periodic table are you...Ch. 2 - Prob. 2.31PAECh. 2 - Prob. 2.32PAECh. 2 - Prob. 2.33PAECh. 2 - 2.30 Using Coulomb’s law, explain how the...Ch. 2 - Prob. 2.35PAECh. 2 - 2.32 Which of the following formulas contains the...Ch. 2 - Prob. 2.37PAECh. 2 - Prob. 2.38PAECh. 2 - Prob. 2.39PAECh. 2 - Prob. 2.40PAECh. 2 - Prob. 2.41PAECh. 2 - Prob. 2.42PAECh. 2 - Describe how a covalently bonded molecule is...Ch. 2 - 2.36 Explain the difference between a molecular...Ch. 2 - 2.37 Why are empirical formulas preferred for...Ch. 2 - 2.38 The molecular formula for the ethylene...Ch. 2 - 239 Polybutadiene is a synthetic elastomer, or...Ch. 2 - 2.40 What distinguished the work of Mendeleev that...Ch. 2 - 2.41 How does the periodic table help to make the...Ch. 2 - 2.42 What is a period in the periodic table? From...Ch. 2 - How do binary compounds with hydrogen illustrate...Ch. 2 - Prob. 2.52PAECh. 2 - 2.43 Name of the group to which each of the...Ch. 2 - Prob. 2.54PAECh. 2 - Prob. 2.55PAECh. 2 - 2.46 Why are nonmetals important even though they...Ch. 2 - Prob. 2.57PAECh. 2 - A materials engineer has filed for a patent for a...Ch. 2 - Prob. 2.59PAECh. 2 - 2.50 A materials engineer wants to make a new...Ch. 2 - Prob. 2.61PAECh. 2 - Prob. 2.62PAECh. 2 - 2.53 What is meant by the phrase organic...Ch. 2 - 2.54 Based on what you have learned in this...Ch. 2 - 2.55 What is a functional group? How does the...Ch. 2 - Prob. 2.66PAECh. 2 - Prob. 2.67PAECh. 2 - Prob. 2.68PAECh. 2 - 2.59 The accompanying figure shows the structure...Ch. 2 - Prob. 2.70PAECh. 2 - Prob. 2.71PAECh. 2 - Prob. 2.72PAECh. 2 - 2.61 Name the following covalent compounds: (a)...Ch. 2 - Prob. 2.74PAECh. 2 - Prob. 2.75PAECh. 2 - Prob. 2.76PAECh. 2 - Prob. 2.77PAECh. 2 - Prob. 2.78PAECh. 2 - Prob. 2.79PAECh. 2 - 2.68 What is a free radical? How are free radicals...Ch. 2 - Prob. 2.81PAECh. 2 - 2.70 Why do you think an inhibitor molecule is...Ch. 2 - 2.71 Use the web to determine the amount of...Ch. 2 - 2.88 Describe how you can identify the isotope, X,...Ch. 2 - 2.90 Naturally occurring europium has an average...Ch. 2 - 2.91 Strontium has four stable isotopes....Ch. 2 - 2.92 A candy manufacturer makes chocolate-covered...Ch. 2 - Prob. 2.88PAECh. 2 - 2.94 Use a molecular level description to...Ch. 2 - 2.95 Engineers who design bicycle frames are...Ch. 2 - 2.96 Use the web to look up the density of...Ch. 2 - 2.97 LDPE has a density in the range of...
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