Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.28PAE
2.24 Identify each of the following species as an anion, a cation, or a molecule. (a)
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 2 Solutions
Chemistry for Engineering Students
Ch. 2 - Name at least three common polymers and give...Ch. 2 - Prob. 2COCh. 2 - Describe the nuclear model for the atom and...Ch. 2 - Prob. 4COCh. 2 - Prob. 5COCh. 2 - Prob. 6COCh. 2 - Prob. 7COCh. 2 - Prob. 8COCh. 2 - Prob. 9COCh. 2 - Prob. 10CO
Ch. 2 - Prob. 2.1PAECh. 2 - How do polymers compare to their respective...Ch. 2 - Look around you and identify several objects that...Ch. 2 - Prob. 2.4PAECh. 2 - The fact that a polymer’s physical properties...Ch. 2 - Use the web to research the amount of PVC polymer...Ch. 2 - Prob. 2.7PAECh. 2 - Prob. 2.8PAECh. 2 - Why is the number of protons called the atomic...Ch. 2 - 2.10 Which isotope in each pair contains more...Ch. 2 - 2.11 Define the term isotope.Ch. 2 - 2.12 Write the complete atomic symbol for each of...Ch. 2 - 2.13 How many electrons, protons, and neutrons are...Ch. 2 - 2.14 Consider the following nuclear symbols. How...Ch. 2 - 2.15 Mercury is 16.716 times more massive than...Ch. 2 - Prob. 2.16PAECh. 2 - Prob. 2.17PAECh. 2 - The element gallium, used in gallium arsenide...Ch. 2 - 2.17 The atomic weight of copper is 63.55 amu....Ch. 2 - The following table presents the abundances and...Ch. 2 - 2.19 Naturally occurring uranium consists of two...Ch. 2 - Prob. 2.22PAECh. 2 - Prob. 2.23PAECh. 2 - Prob. 2.24PAECh. 2 - Prob. 2.25PAECh. 2 - 2.22 Provide the symbol of the following...Ch. 2 - Prob. 2.27PAECh. 2 - 2.24 Identify each of the following species as an...Ch. 2 - 2.25 Write the atomic symbol for the element whose...Ch. 2 - 2.26 In what region of the periodic table are you...Ch. 2 - Prob. 2.31PAECh. 2 - Prob. 2.32PAECh. 2 - Prob. 2.33PAECh. 2 - 2.30 Using Coulomb’s law, explain how the...Ch. 2 - Prob. 2.35PAECh. 2 - 2.32 Which of the following formulas contains the...Ch. 2 - Prob. 2.37PAECh. 2 - Prob. 2.38PAECh. 2 - Prob. 2.39PAECh. 2 - Prob. 2.40PAECh. 2 - Prob. 2.41PAECh. 2 - Prob. 2.42PAECh. 2 - Describe how a covalently bonded molecule is...Ch. 2 - 2.36 Explain the difference between a molecular...Ch. 2 - 2.37 Why are empirical formulas preferred for...Ch. 2 - 2.38 The molecular formula for the ethylene...Ch. 2 - 239 Polybutadiene is a synthetic elastomer, or...Ch. 2 - 2.40 What distinguished the work of Mendeleev that...Ch. 2 - 2.41 How does the periodic table help to make the...Ch. 2 - 2.42 What is a period in the periodic table? From...Ch. 2 - How do binary compounds with hydrogen illustrate...Ch. 2 - Prob. 2.52PAECh. 2 - 2.43 Name of the group to which each of the...Ch. 2 - Prob. 2.54PAECh. 2 - Prob. 2.55PAECh. 2 - 2.46 Why are nonmetals important even though they...Ch. 2 - Prob. 2.57PAECh. 2 - A materials engineer has filed for a patent for a...Ch. 2 - Prob. 2.59PAECh. 2 - 2.50 A materials engineer wants to make a new...Ch. 2 - Prob. 2.61PAECh. 2 - Prob. 2.62PAECh. 2 - 2.53 What is meant by the phrase organic...Ch. 2 - 2.54 Based on what you have learned in this...Ch. 2 - 2.55 What is a functional group? How does the...Ch. 2 - Prob. 2.66PAECh. 2 - Prob. 2.67PAECh. 2 - Prob. 2.68PAECh. 2 - 2.59 The accompanying figure shows the structure...Ch. 2 - Prob. 2.70PAECh. 2 - Prob. 2.71PAECh. 2 - Prob. 2.72PAECh. 2 - 2.61 Name the following covalent compounds: (a)...Ch. 2 - Prob. 2.74PAECh. 2 - Prob. 2.75PAECh. 2 - Prob. 2.76PAECh. 2 - Prob. 2.77PAECh. 2 - Prob. 2.78PAECh. 2 - Prob. 2.79PAECh. 2 - 2.68 What is a free radical? How are free radicals...Ch. 2 - Prob. 2.81PAECh. 2 - 2.70 Why do you think an inhibitor molecule is...Ch. 2 - 2.71 Use the web to determine the amount of...Ch. 2 - 2.88 Describe how you can identify the isotope, X,...Ch. 2 - 2.90 Naturally occurring europium has an average...Ch. 2 - 2.91 Strontium has four stable isotopes....Ch. 2 - 2.92 A candy manufacturer makes chocolate-covered...Ch. 2 - Prob. 2.88PAECh. 2 - 2.94 Use a molecular level description to...Ch. 2 - 2.95 Engineers who design bicycle frames are...Ch. 2 - 2.96 Use the web to look up the density of...Ch. 2 - 2.97 LDPE has a density in the range of...
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- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
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