Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.43PAE
Describe how a covalently bonded molecule is different from compounds that are either ionic or metallic.
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4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
Chapter 2 Solutions
Chemistry for Engineering Students
Ch. 2 - Name at least three common polymers and give...Ch. 2 - Prob. 2COCh. 2 - Describe the nuclear model for the atom and...Ch. 2 - Prob. 4COCh. 2 - Prob. 5COCh. 2 - Prob. 6COCh. 2 - Prob. 7COCh. 2 - Prob. 8COCh. 2 - Prob. 9COCh. 2 - Prob. 10CO
Ch. 2 - Prob. 2.1PAECh. 2 - How do polymers compare to their respective...Ch. 2 - Look around you and identify several objects that...Ch. 2 - Prob. 2.4PAECh. 2 - The fact that a polymer’s physical properties...Ch. 2 - Use the web to research the amount of PVC polymer...Ch. 2 - Prob. 2.7PAECh. 2 - Prob. 2.8PAECh. 2 - Why is the number of protons called the atomic...Ch. 2 - 2.10 Which isotope in each pair contains more...Ch. 2 - 2.11 Define the term isotope.Ch. 2 - 2.12 Write the complete atomic symbol for each of...Ch. 2 - 2.13 How many electrons, protons, and neutrons are...Ch. 2 - 2.14 Consider the following nuclear symbols. How...Ch. 2 - 2.15 Mercury is 16.716 times more massive than...Ch. 2 - Prob. 2.16PAECh. 2 - Prob. 2.17PAECh. 2 - The element gallium, used in gallium arsenide...Ch. 2 - 2.17 The atomic weight of copper is 63.55 amu....Ch. 2 - The following table presents the abundances and...Ch. 2 - 2.19 Naturally occurring uranium consists of two...Ch. 2 - Prob. 2.22PAECh. 2 - Prob. 2.23PAECh. 2 - Prob. 2.24PAECh. 2 - Prob. 2.25PAECh. 2 - 2.22 Provide the symbol of the following...Ch. 2 - Prob. 2.27PAECh. 2 - 2.24 Identify each of the following species as an...Ch. 2 - 2.25 Write the atomic symbol for the element whose...Ch. 2 - 2.26 In what region of the periodic table are you...Ch. 2 - Prob. 2.31PAECh. 2 - Prob. 2.32PAECh. 2 - Prob. 2.33PAECh. 2 - 2.30 Using Coulomb’s law, explain how the...Ch. 2 - Prob. 2.35PAECh. 2 - 2.32 Which of the following formulas contains the...Ch. 2 - Prob. 2.37PAECh. 2 - Prob. 2.38PAECh. 2 - Prob. 2.39PAECh. 2 - Prob. 2.40PAECh. 2 - Prob. 2.41PAECh. 2 - Prob. 2.42PAECh. 2 - Describe how a covalently bonded molecule is...Ch. 2 - 2.36 Explain the difference between a molecular...Ch. 2 - 2.37 Why are empirical formulas preferred for...Ch. 2 - 2.38 The molecular formula for the ethylene...Ch. 2 - 239 Polybutadiene is a synthetic elastomer, or...Ch. 2 - 2.40 What distinguished the work of Mendeleev that...Ch. 2 - 2.41 How does the periodic table help to make the...Ch. 2 - 2.42 What is a period in the periodic table? From...Ch. 2 - How do binary compounds with hydrogen illustrate...Ch. 2 - Prob. 2.52PAECh. 2 - 2.43 Name of the group to which each of the...Ch. 2 - Prob. 2.54PAECh. 2 - Prob. 2.55PAECh. 2 - 2.46 Why are nonmetals important even though they...Ch. 2 - Prob. 2.57PAECh. 2 - A materials engineer has filed for a patent for a...Ch. 2 - Prob. 2.59PAECh. 2 - 2.50 A materials engineer wants to make a new...Ch. 2 - Prob. 2.61PAECh. 2 - Prob. 2.62PAECh. 2 - 2.53 What is meant by the phrase organic...Ch. 2 - 2.54 Based on what you have learned in this...Ch. 2 - 2.55 What is a functional group? How does the...Ch. 2 - Prob. 2.66PAECh. 2 - Prob. 2.67PAECh. 2 - Prob. 2.68PAECh. 2 - 2.59 The accompanying figure shows the structure...Ch. 2 - Prob. 2.70PAECh. 2 - Prob. 2.71PAECh. 2 - Prob. 2.72PAECh. 2 - 2.61 Name the following covalent compounds: (a)...Ch. 2 - Prob. 2.74PAECh. 2 - Prob. 2.75PAECh. 2 - Prob. 2.76PAECh. 2 - Prob. 2.77PAECh. 2 - Prob. 2.78PAECh. 2 - Prob. 2.79PAECh. 2 - 2.68 What is a free radical? How are free radicals...Ch. 2 - Prob. 2.81PAECh. 2 - 2.70 Why do you think an inhibitor molecule is...Ch. 2 - 2.71 Use the web to determine the amount of...Ch. 2 - 2.88 Describe how you can identify the isotope, X,...Ch. 2 - 2.90 Naturally occurring europium has an average...Ch. 2 - 2.91 Strontium has four stable isotopes....Ch. 2 - 2.92 A candy manufacturer makes chocolate-covered...Ch. 2 - Prob. 2.88PAECh. 2 - 2.94 Use a molecular level description to...Ch. 2 - 2.95 Engineers who design bicycle frames are...Ch. 2 - 2.96 Use the web to look up the density of...Ch. 2 - 2.97 LDPE has a density in the range of...
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