Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 2, Problem 2.70AP
(a)
Interpretation Introduction
Interpretation:
The ground state electronic configuration of Nitrogen has to be given.
Concept Introduction:
The distribution of electrons in various orbitals is known as electronic configuration.
The filling of orbitals in the ground state is determined by the following rule:
Aufbau Principle:
The Aufbau principle states that in the ground state of an atom the orbital with lower energy are filled up first before the filling of the orbital with ah higher energy commences.
(b)
Interpretation Introduction
Interpretation:
The ground state electronic configuration of Argon has to be given.
Concept Introduction:
Refer to part (a).
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 2 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 2.1 - Give the symbol for each element. a. calcium, a...Ch. 2.1 - Prob. 2.2PCh. 2.1 - Give the name corresponding to each element...Ch. 2.1 - Locate each element in the periodic table and...Ch. 2.1 - Classify each micronutrient in Figure 2.2 as a...Ch. 2.1 - Identify the elements used in each example of...Ch. 2.1 - Identify the elements in each chemical formula,...Ch. 2.1 - Prob. 2.8PCh. 2.2 - Prob. 2.9PCh. 2.2 - Prob. 2.10P
Ch. 2.2 - Prob. 2.11PCh. 2.2 - Prob. 2.12PCh. 2.2 - Prob. 2.13PCh. 2.3 - Prob. 2.14PCh. 2.3 - Prob. 2.15PCh. 2.3 - Prob. 2.16PCh. 2.3 - Prob. 2.17PCh. 2.3 - Prob. 2.18PCh. 2.4 - Prob. 2.19PCh. 2.4 - Give the period and group number for each element:...Ch. 2.4 - Prob. 2.21PCh. 2.4 - Prob. 2.22PCh. 2.5 - Prob. 2.23PCh. 2.6 - Prob. 2.24PCh. 2.6 - Prob. 2.25PCh. 2.6 - Prob. 2.26PCh. 2.7 - Identify the total number of electrons, the number...Ch. 2.7 - Prob. 2.28PCh. 2.7 - Prob. 2.29PCh. 2.8 - Which element in each pair has the larger atomic...Ch. 2.8 - Which element in each pair has the higher...Ch. 2.8 - Prob. 2.32PCh. 2 - Identify the elements used in each example of...Ch. 2 - Prob. 2.34UKCCh. 2 - Prob. 2.35UKCCh. 2 - Prob. 2.36UKCCh. 2 - Prob. 2.37UKCCh. 2 - Prob. 2.38UKCCh. 2 - Prob. 2.39UKCCh. 2 - Prob. 2.40UKCCh. 2 - Prob. 2.41UKCCh. 2 - Prob. 2.42UKCCh. 2 - Prob. 2.43UKCCh. 2 - Prob. 2.44UKCCh. 2 - Prob. 2.45APCh. 2 - Prob. 2.46APCh. 2 - Prob. 2.47APCh. 2 - Identify the elements in each chemical formula and...Ch. 2 - Prob. 2.49APCh. 2 - Prob. 2.50APCh. 2 - Prob. 2.51APCh. 2 - Prob. 2.52APCh. 2 - Prob. 2.53APCh. 2 - Prob. 2.54APCh. 2 - Prob. 2.55APCh. 2 - Prob. 2.56APCh. 2 - Prob. 2.57APCh. 2 - Prob. 2.58APCh. 2 - The most common isotope of oxygen has a mass...Ch. 2 - Prob. 2.60APCh. 2 - Prob. 2.61APCh. 2 - Prob. 2.62APCh. 2 - Prob. 2.63APCh. 2 - Prob. 2.64APCh. 2 - Prob. 2.65APCh. 2 - Prob. 2.66APCh. 2 - Prob. 2.67APCh. 2 - Prob. 2.68APCh. 2 - Prob. 2.69APCh. 2 - Prob. 2.70APCh. 2 - Prob. 2.71APCh. 2 - Prob. 2.72APCh. 2 - Prob. 2.73APCh. 2 - Prob. 2.74APCh. 2 - Prob. 2.75APCh. 2 - Prob. 2.76APCh. 2 - Prob. 2.77APCh. 2 - Prob. 2.78APCh. 2 - Prob. 2.79APCh. 2 - Prob. 2.80APCh. 2 - Prob. 2.81APCh. 2 - Prob. 2.82APCh. 2 - Prob. 2.83APCh. 2 - Arrange the elements in each group in order of...Ch. 2 - Prob. 2.85APCh. 2 - Prob. 2.86APCh. 2 - Answer the following questions about...Ch. 2 - Prob. 2.88APCh. 2 - Prob. 2.89APCh. 2 - (a) What is the chemical formula for...Ch. 2 - Prob. 2.91CPCh. 2 - Prob. 2.93BTCCh. 2 - Prob. 2.95BTC
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