Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
9th Edition
ISBN: 9781305968608
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.54E
How many grams of
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 2 Solutions
Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
Ch. 2 - Draw a formula for each of the following molecules...Ch. 2 - Prob. 2.2ECh. 2 - Write formulas for the following molecules using...Ch. 2 - Write formulas for the following molecules using...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Prob. 2.9ECh. 2 - Prob. 2.10E
Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Prob. 2.15ECh. 2 - Prob. 2.16ECh. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Prob. 2.19ECh. 2 - Prob. 2.20ECh. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write the symbols and names for two elements whose...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - What are the symbol and name for an element whose...Ch. 2 - In the first 36 elements, 6 elements have atoms...Ch. 2 - What are the symbol and name of the element whose...Ch. 2 - Prob. 2.29ECh. 2 - Prob. 2.30ECh. 2 - The molecular weight was determined for a gas that...Ch. 2 - A flammable gas is known to contain only carbon...Ch. 2 - Glycine, an amino acid found in proteins, has a...Ch. 2 - Serine, an amino acid found in proteins, has a...Ch. 2 - Naturally occurring sodium has a single isotope....Ch. 2 - Naturally occurring aluminum has a single isotope....Ch. 2 - Calculate the atomic weight of lithium on the...Ch. 2 - Calculate the atomic weight of boron on the basis...Ch. 2 - Calculate the atomic weight of silicon on the...Ch. 2 - Calculate the atomic weight of copper on the basis...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Prob. 2.47ECh. 2 - Refer to the periodic table and calculate the...Ch. 2 - Prob. 2.49ECh. 2 - Prob. 2.50ECh. 2 - Answer the following questions based on the...Ch. 2 - Answer the following questions based on...Ch. 2 - How many moles of N2O5 contain the same number of...Ch. 2 - How many grams of C2H6O contain the same number of...Ch. 2 - Prob. 2.55ECh. 2 - Determine the mass percentage of hydrogen in CH4...Ch. 2 - Prob. 2.57ECh. 2 - Prob. 2.58ECh. 2 - Urea (CH4N2O) and ammonium sulfate (N2H8SO4) are...Ch. 2 - Prob. 2.60ECh. 2 - Prob. 2.61ECh. 2 - Prob. 2.62ECh. 2 - Prob. 2.63ECh. 2 - The mass of a single carbon 12 atom is 1.991023g....Ch. 2 - Prob. 2.65ECh. 2 - Prob. 2.66ECh. 2 - a. Explain how atoms of different elements differ...Ch. 2 - The atomic weight of aluminum is 26.98u and the...Ch. 2 - Answer the question in the caption of Figure 2.3...Ch. 2 - Answer the question in the caption of Figure 2.5...Ch. 2 - Prob. 2.71ECh. 2 - Prob. 2.72ECh. 2 - Prob. 2.73ECh. 2 - Prob. 2.74ECh. 2 - Prob. 2.75ECh. 2 - Which one of the following substances is a...Ch. 2 - Which of the following is true about compounds?...Ch. 2 - C1734l has a.17 protons, 17 electrons, and 17...Ch. 2 - If two atoms are isotopes, they will a.have same...Ch. 2 - Copper (Cu) has an atomic number of 29 and a mass...Ch. 2 - Atoms are electrically neutral. This means that an...Ch. 2 - The negative charged particle found within the...Ch. 2 - Prob. 2.83ECh. 2 - Prob. 2.84ECh. 2 - The mass of an atom is almost entirely contributed...Ch. 2 - Which of the following is the chemical symbol for...Ch. 2 - Prob. 2.87ECh. 2 - What is the mass number of an atom with 60...Ch. 2 - Which of the following represents Avogadros...Ch. 2 - Which of the following has the greatest number of...Ch. 2 - The formula of carbon dioxide is CO2. Its...Ch. 2 - What is the molar mass of calcium oxide, CaO? a....Ch. 2 - How many grams are contained in 0.200mol of...Ch. 2 - How many moles are contained in a 54.0g sample of...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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