Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
9th Edition
ISBN: 9781305968608
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.64E
The mass of a single carbon
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 2 Solutions
Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
Ch. 2 - Draw a formula for each of the following molecules...Ch. 2 - Prob. 2.2ECh. 2 - Write formulas for the following molecules using...Ch. 2 - Write formulas for the following molecules using...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Prob. 2.9ECh. 2 - Prob. 2.10E
Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Prob. 2.15ECh. 2 - Prob. 2.16ECh. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Prob. 2.19ECh. 2 - Prob. 2.20ECh. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write the symbols and names for two elements whose...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - What are the symbol and name for an element whose...Ch. 2 - In the first 36 elements, 6 elements have atoms...Ch. 2 - What are the symbol and name of the element whose...Ch. 2 - Prob. 2.29ECh. 2 - Prob. 2.30ECh. 2 - The molecular weight was determined for a gas that...Ch. 2 - A flammable gas is known to contain only carbon...Ch. 2 - Glycine, an amino acid found in proteins, has a...Ch. 2 - Serine, an amino acid found in proteins, has a...Ch. 2 - Naturally occurring sodium has a single isotope....Ch. 2 - Naturally occurring aluminum has a single isotope....Ch. 2 - Calculate the atomic weight of lithium on the...Ch. 2 - Calculate the atomic weight of boron on the basis...Ch. 2 - Calculate the atomic weight of silicon on the...Ch. 2 - Calculate the atomic weight of copper on the basis...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Prob. 2.47ECh. 2 - Refer to the periodic table and calculate the...Ch. 2 - Prob. 2.49ECh. 2 - Prob. 2.50ECh. 2 - Answer the following questions based on the...Ch. 2 - Answer the following questions based on...Ch. 2 - How many moles of N2O5 contain the same number of...Ch. 2 - How many grams of C2H6O contain the same number of...Ch. 2 - Prob. 2.55ECh. 2 - Determine the mass percentage of hydrogen in CH4...Ch. 2 - Prob. 2.57ECh. 2 - Prob. 2.58ECh. 2 - Urea (CH4N2O) and ammonium sulfate (N2H8SO4) are...Ch. 2 - Prob. 2.60ECh. 2 - Prob. 2.61ECh. 2 - Prob. 2.62ECh. 2 - Prob. 2.63ECh. 2 - The mass of a single carbon 12 atom is 1.991023g....Ch. 2 - Prob. 2.65ECh. 2 - Prob. 2.66ECh. 2 - a. Explain how atoms of different elements differ...Ch. 2 - The atomic weight of aluminum is 26.98u and the...Ch. 2 - Answer the question in the caption of Figure 2.3...Ch. 2 - Answer the question in the caption of Figure 2.5...Ch. 2 - Prob. 2.71ECh. 2 - Prob. 2.72ECh. 2 - Prob. 2.73ECh. 2 - Prob. 2.74ECh. 2 - Prob. 2.75ECh. 2 - Which one of the following substances is a...Ch. 2 - Which of the following is true about compounds?...Ch. 2 - C1734l has a.17 protons, 17 electrons, and 17...Ch. 2 - If two atoms are isotopes, they will a.have same...Ch. 2 - Copper (Cu) has an atomic number of 29 and a mass...Ch. 2 - Atoms are electrically neutral. This means that an...Ch. 2 - The negative charged particle found within the...Ch. 2 - Prob. 2.83ECh. 2 - Prob. 2.84ECh. 2 - The mass of an atom is almost entirely contributed...Ch. 2 - Which of the following is the chemical symbol for...Ch. 2 - Prob. 2.87ECh. 2 - What is the mass number of an atom with 60...Ch. 2 - Which of the following represents Avogadros...Ch. 2 - Which of the following has the greatest number of...Ch. 2 - The formula of carbon dioxide is CO2. Its...Ch. 2 - What is the molar mass of calcium oxide, CaO? a....Ch. 2 - How many grams are contained in 0.200mol of...Ch. 2 - How many moles are contained in a 54.0g sample of...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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