Which of the following bases are strong enough to deprotonate CH 3 CH 2 CH 2 C ≡ CH ( p K a = 25 ) , so that equilibrium favors the products: (a) H 2 O ; (b) NaOH ; (c) NaNH 2 ; (d) NH 3 ; (e) NaH ; (f) CH 3 Li ?
Which of the following bases are strong enough to deprotonate CH 3 CH 2 CH 2 C ≡ CH ( p K a = 25 ) , so that equilibrium favors the products: (a) H 2 O ; (b) NaOH ; (c) NaNH 2 ; (d) NH 3 ; (e) NaH ; (f) CH 3 Li ?
Solution Summary: The author explains the Bronsted-Lowry theory that when an acid donates a proton, the species formed is known as conjugate acid.
Which of the following bases are strong enough to deprotonate
CH
3
CH
2
CH
2
C
≡
CH
(
p
K
a
=
25
)
, so that equilibrium favors the products: (a)
H
2
O
; (b)
NaOH
; (c)
NaNH
2
; (d)
NH
3
; (e)
NaH
; (f)
CH
3
Li
?
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
Don't used Ai solution
In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 2 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
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