(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 149.2 + 0.034 + 2000.34 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 149.2 + 0.034 + 2000.34 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Solution Summary: The author explains that the number of significant digits in the answer should be determined by evaluating the given expression.
The number of significant digits in the answer should be determined by evaluating the given expression.
(149.2+0.034+2000.34).
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(b)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
(1.0322×103+4.34×103)
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(c)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
4.03×10−2−2.044×10−3
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(d)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
2.094×105−1.073×106
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
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