(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 0.0432 ) ( 2.909 ) ( 4.43 × 10 8 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 0.0432 ) ( 2.909 ) ( 4.43 × 10 8 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
The number of significant digits in the answer should be determined by evaluating the given expression.
(0.0432)(2.909)(4.43×108).
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Expert Solution
Answer to Problem 139AP
0.557×108.
Explanation of Solution
The expression is (0.0432)(2.909)(4.43×108). By calculating it we get, 0.556712784×108
In multiplication, the number of significant figures in final answer should be equal to the minimum number of significant figures in the calculation. The number with minimum number of significant figure is 4.43×108 thus, minimum number of significant figure is 3, thus, final answer should be rounded off up to three significant figures which is equal to 0.557×108.
Interpretation Introduction
(b)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
(0.8922)/[(0.00932)(4.03×102)]
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Expert Solution
Answer to Problem 139AP
23.74×10−2.
Explanation of Solution
The given expression is (0.8922)/[(0.00932)(4.03×102)]. By calculating it we get, 23.7542465×10−2
In multiplication and division, the number of significant figures in final answer should be equal to the minimum number of significant figures in the calculation. The number with minimum number of significant figure is 0.8922 thus, minimum number of significant figure is 4, thus, final answer should be rounded off up to four significant figures which is equal to 23.74×10−2.
Interpretation Introduction
(c)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
(3.923×102)(2.94)(4.093×10−3)
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Expert Solution
Answer to Problem 139AP
47.2×10−1.
Explanation of Solution
The given expression is (3.923×102)(2.94)(4.093×10−3). By calculating it we get, 47.20710666×10−1
In multiplication, the number of significant figures in final answer should be equal to the minimum number of significant figures in the calculation. The number with minimum number of significant figure is 2.94 thus, minimum number of significant figure is 3, thus, final answer should be rounded off up to three significant figures which is equal to 47.2×10−1.
Interpretation Introduction
(d)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
(4.9211)(0.04434)/[(0.000934)(2.892×10−7)]
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Expert Solution
Answer to Problem 139AP
80.78×107.
Explanation of Solution
The given expression is (4.9211)(0.04434)/[(0.000934)(2.892×10−7)]. By calculating it we get, 80.78164899997334×107
In multiplication and division, the number of significant figures in final answer should be equal to the minimum number of significant figures in the calculation. The number with minimum number of significant figure is 2.892×10−7 thus, minimum number of significant figure is 4, thus, final answer should be rounded off up to four significant figures which is equal to 80.78×107.
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6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.
Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell