Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 1.9B, Problem 1.9P

(a)

Interpretation Introduction

To draw: The important resonating structures of the given cation.

Interpretation: The important resonating structures of the given cation are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance, shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

(b)

Interpretation Introduction

To draw: The important resonating structures of the given cation.

Interpretation: The important resonating structures of the given cation are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

(c)

Interpretation Introduction

To draw: The important resonating structures of the given cation.

Interpretation: The important resonating structures of the given cation are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

(d)

Interpretation Introduction

To draw: The important resonating structures of the given anion.

Interpretation: The important resonating structures of the given anion are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

(e)

Interpretation Introduction

To draw: The important resonating structures of the given anion.

Interpretation: The important resonating structures of the given anion are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

(f)

Interpretation Introduction

To draw: The important resonating structures of the given anion.

Interpretation: The important resonating structures of the given anion are to be drawn.

Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs. Positive and negative charges decide the high or low electron density areas.

Large conjugation of lone pairs, double bond, triple bond and charge on atoms enhances the resonance.

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Chapter 1 Solutions

Organic Chemistry (9th Edition)

Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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